Solution NMR of synthetic cavity containing supramolecular systems: what have we learned on and from?

Y Cohen, S Slovak, L Avram - Chemical Communications, 2021 - pubs.rsc.org
NMR has been instrumental in studies of both the structure and dynamics of molecular
systems for decades, so it is not surprising that NMR has played a pivotal role in the study of …

Insights into the self-assembly of giant polyoxomolybdates from building blocks to supramolecular structures

K Li, KL Zhu, LP Cui, JJ Chen - Dalton Transactions, 2023 - pubs.rsc.org
Giant polyoxomolybdates are a special class of polyoxometalate clusters which can bridge
the gap between small molecule clusters and large polymeric entities. Besides, giant …

Hofmeister effect in the Keggin-type polyoxotungstate series

S Yao, C Falaise, AA Ivanov, N Leclerc… - Inorganic Chemistry …, 2021 - pubs.rsc.org
The chaotropic character of Keggin-type polyoxotungstate anions was evaluated with
respect to their ability to bind to γ-cyclodextrin (γ-CD) by varying the global charge density of …

Bacterial hyperpolarization modulated by polyoxometalates for solutions of antibiotic resistance

K Chen, Q Yu, Y Liu, P Yin - Journal of Inorganic Biochemistry, 2021 - Elsevier
Develo** strategies against the antibiotic resistance is a major global challenge for public
health. Here, we report the synergy of the combination of Preyssler-type polyoxometalates …

Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins

K Grzhegorzhevskii, M Haouas, M Lion… - Chemical …, 2023 - pubs.rsc.org
Noncovalent ionic interactions between nanosized Keplerate-type capsules {Mo132} and
tetra-cationic porphyrins have been investigated in aqueous solution using small-angle X …

Embedding alkenes within an icosahedral inorganic fullerene {(NH 4) 42 [Mo 132 O 372 (L) 30 (H 2 O) 72]} for trap** volatile organics

RW Pow, W Xuan, DL Long, NL Bell, L Cronin - Chemical Science, 2020 - pubs.rsc.org
Eight alkene-functionalized molybdenum-based spherical Keplerate-type (inorganic
fullerene) structures have been obtained via both direct and multistep synthetic approaches …

Enantioselective Recognition of Racemic Amino Alcohols in Aqueous Solution by Chiral Metal‐Oxide Keplerate {Mo132} Cluster Capsules

RW Pow, ZL Sinclair, NL Bell, N Watfa… - … A European Journal, 2021 - Wiley Online Library
Determining the relative configuration or enantiomeric excess of a substance may be
achieved using NMR spectroscopy by employing chiral shift reagents (CSRs). Such …

Guest transition metals in host inorganic nanocapsules: single sites, discrete electron transfer, and atomic scale structure

E Haviv, B Chen, R Carmieli, L Houben… - Journal of the …, 2020 - ACS Publications
Host–guest solution chemistry with a wide range of organic hosts is an important and
established research area, while the use of inorganic hosts is a more nascent area of …

Minor change in the length of carbon chain has a great influence on the antitumor effect of paclitaxel-fatty alcohol prodrug nanoassemblies: Small roles, big impacts

X Wang, L Li, D Wang, S Zuo, T Liu, F Dong, X Zhang… - Nano Research, 2022 - Springer
Prodrug-based nanoassembly emerges as a hopeful way for the efficient delivery of
antitumor drugs, with carrier-free structure and ultra-high drug loading. Carbon chains are …

Collective Effects of Multiple Fluorine Atoms Causing π‐philic Characteristic within a Caged Polyoxometalate Framework

C Murata, A Nakashuku, Y Shichibu… - … –A European Journal, 2024 - Wiley Online Library
Perfluorination brings about distinctive properties arising from the unusual nature of the F
element, which have been extensively developed in materials science and chemistry …