Supramolecular polymers: Recent advances based on the types of underlying interactions

HQ Peng, W Zhu, WJ Guo, Q Li, S Ma, C Bucher… - Progress in Polymer …, 2023 - Elsevier
Supramolecular polymers are, in broad brushstrokes, self-assembled structures built up from
small building blocks via the use of noncovalent interactions. In favorable cases …

Can super-resolution microscopy become a standard characterization technique for materials chemistry?

S Dhiman, T Andrian, BS Gonzalez, MME Tholen… - Chemical …, 2022 - pubs.rsc.org
The characterization of newly synthesized materials is a cornerstone of all chemistry and
nanotechnology laboratories. For this purpose, a wide array of analytical techniques have …

Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization

E Weyandt, L Leanza, R Capelli, GM Pavan… - Nature …, 2022 - nature.com
Multi-component systems often display convoluted behavior, pathway complexity and
coupled equilibria. In recent years, several ways to control complex systems by manipulating …

Controlled noncovalent synthesis of secondary supramolecular polymers

S Sarkar, R Laishram, D Deb… - Journal of the American …, 2023 - ACS Publications
Dynamic supramolecular polymers, with their functional similarities to classical covalent
polymers and their adaptive and self-repairing nature reminiscent of biological assemblies …

Chirality-controlled supramolecular donor–acceptor copolymerization with distinct energy transfer efficiency

R Liao, F Wang, Y Guo, Y Han… - Journal of the American …, 2022 - ACS Publications
Chirality delivers substantial value to the field of supramolecular polymers, not only serving
as a probe to monitor the dynamic assembly process but providing access to chiroptical …

Pathway complexity in supramolecular copolymerization and blocky star copolymers by a hetero-seeding effect

P Khanra, AK Singh, L Roy, A Das - Journal of the American …, 2023 - ACS Publications
This study unravels the intricate kinetic and thermodynamic pathways involved in the
supramolecular copolymerization of the two chiral dipolar naphthalene monoimide (NMI) …

Secondary nucleation-triggered physical cross-links and tunable stiffness in seeded supramolecular hydrogels

R Laishram, S Sarkar, I Seth, N Khatun… - Journal of the …, 2022 - ACS Publications
Mechanistic understanding and the control of molecular self-assembly at all hierarchical
levels remain grand challenges in supramolecular chemistry. Functional realization of …

Chiral arylene diimide phosphors: circularly polarized ambient phosphorescence from bischromophoric pyromellitic diimides

S Garain, S Sarkar, B Chandra Garain… - Angewandte Chemie …, 2022 - Wiley Online Library
Chiral organic phosphors with circularly polarized room‐temperature phosphorescence
(CPP) provide new prospects to the realm of circularly polarized luminescence (CPL) …

Crystallization‐Driven Controlled Two‐Dimensional (2D) Assemblies from Chromophore‐Appended Poly (L‐lactide) s: Highly Efficient Energy Transfer on a 2D …

A Rajak, A Das - Angewandte Chemie International Edition, 2022 - Wiley Online Library
A rational approach towards precision two‐dimensional (2D) assemblies by crystallization‐
driven self‐assembly (CDSA) of poly (L‐lactides)(PLLAs), end‐capped with dipolar dyes like …

Two‐dimensional Supramolecular Polymers Based on Selectively Recognized Aromatic Cation‐π and Donor‐Acceptor Motifs for Photocatalytic Hydrogen Evolution

Z Gao, L Shi, F Yan, Y Han, W Yuan… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Two‐dimensional (2D) organic polymers have recently received considerable
interest, especially those whose architectures are held together via supramolecular …