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PET recycling under mild conditions via substituent-modulated intramolecular hydrolysis
Catalytic depolymerization represents a promising approach for the closed-loop recycling of
plastic wastes. Here, we report a knowledge-driven catalyst development for poly (ethylene …
plastic wastes. Here, we report a knowledge-driven catalyst development for poly (ethylene …
Three‐Dimensional Covalent Organic Frameworks Based on Linear and Trigonal Linkers for High‐Performance H2O2 Photosynthesis
RM Zhu, Y Liu, WK Han, JD Feng… - Angewandte Chemie …, 2025 - Wiley Online Library
The design of three‐dimensional covalent organic frameworks (3D COFs) using linear and
trigonal linkers remains challenging due to the difficulty in achieving a specific non‐planar …
trigonal linkers remains challenging due to the difficulty in achieving a specific non‐planar …
Exploring the structural attributes of Yoda1 for the development of new-generation Piezo1 agonist Yaddle1 as a vaccine adjuvant targeting optimal T cell activation
S Goon, C Shiu Chen Liu… - Journal of Medicinal …, 2024 - ACS Publications
Piezo1, a mechano-activated ion channel, has wide-ranging physiological and therapeutic
implications, with the ongoing development of specific agonists unveiling cellular responses …
implications, with the ongoing development of specific agonists unveiling cellular responses …
Dissecting solvent effects on hydrogen bonding
NY Meredith, S Borsley, IV Smolyar… - Angewandte Chemie …, 2022 - Wiley Online Library
The experimental isolation of H‐bond energetics from the typically dominant influence of the
solvent remains challenging. Here we use synthetic molecular balances to quantify …
solvent remains challenging. Here we use synthetic molecular balances to quantify …
Substituent and Heteroatom Effects on π–π Interactions: Evidence That Parallel-Displaced π-Stacking is Not Driven by Quadrupolar Electrostatics
Stacking interactions are a recurring motif in supramolecular chemistry and biochemistry,
where a persistent theme is a preference for parallel-displaced aromatic rings rather than …
where a persistent theme is a preference for parallel-displaced aromatic rings rather than …
The interplay between hydrogen and halogen bonding: substituent effects and their role in the hydrogen bond enhanced halogen bond
J Sun, DA Decato, VS Bryantsev, EA John… - Chemical …, 2023 - pubs.rsc.org
The hydrogen bond enhanced halogen bond (HBeXB) has recently been used to effectively
improve anion binding, organocatalysis, and protein structure/function. In this study, we …
improve anion binding, organocatalysis, and protein structure/function. In this study, we …
The Stability of Hydrogen‐Bonded Ion‐Pair Complex Unexpectedly Increases with Increasing Solvent Polarity
The generally observed decrease of the electrostatic energy in the complex with increasing
solvent polarity has led to the assumption that the stability of the complexes with ion‐pair …
solvent polarity has led to the assumption that the stability of the complexes with ion‐pair …
Quantifying interactions and solvent effects using molecular balances and model complexes
A Elmi, SL Cockroft - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus Where the basic units of molecular chemistry are the bonds within molecules,
supramolecular chemistry is based on the interactions that occur between molecules …
supramolecular chemistry is based on the interactions that occur between molecules …
Dissection of the Polar and Non‐Polar Contributions to Aromatic Stacking Interactions in Solution
Aromatic stacking interactions have been a matter of study and debate due to their crucial
role in chemical and biological systems. The strong dependence on orientation and solvent …
role in chemical and biological systems. The strong dependence on orientation and solvent …
Probing Non-Covalent Interactions through Molecular Balances: A REG-IQA Study
F Falcioni, S Bennett, P Stroer-Jarvis, PLA Popelier - Molecules, 2024 - mdpi.com
The interaction energies of two series of molecular balances (1-X with X= H, Me, OMe,
NMe2 and 2-Y with Y= H, CN, NO2, OMe, NMe2) designed to probe carbonyl… carbonyl …
NMe2 and 2-Y with Y= H, CN, NO2, OMe, NMe2) designed to probe carbonyl… carbonyl …