Heteroatom-based diradical (oid) s

A Hinz, J Bresien, F Breher, A Schulz - Chemical Reviews, 2023 - ACS Publications
Heteroatom-centered diradical (oid) s have been in the focus of molecular main group
chemistry for nearly 30 years. During this time, the diradical concept has evolved and the …

Using coherence to enhance function in chemical and biophysical systems

GD Scholes, GR Fleming, LX Chen, A Aspuru-Guzik… - Nature, 2017 - nature.com
Coherence phenomena arise from interference, or the addition, of wave-like amplitudes with
fixed phase differences. Although coherence has been shown to yield transformative ways …

Direct observation of geometric-phase interference in dynamics around a conical intersection

CH Valahu, VC Olaya-Agudelo, RJ MacDonell… - Nature Chemistry, 2023 - nature.com
Conical intersections are ubiquitous in chemistry and physics, often governing processes
such as light harvesting, vision, photocatalysis and chemical reactivity. They act as funnels …

Jahn–Teller and Pseudo-Jahn–Teller Effects: From particular features to general tools in exploring molecular and solid state properties

IB Bersuker - Chemical Reviews, 2020 - ACS Publications
In a generalization of the latest achievements in this field, and as a pattern of massive
applications, we present here the Jahn–Teller effect (JTE) and pseudo-JTE (PJTE) as …

Advances in lead-free perovskite single crystals: Fundamentals and applications

NK Tailor, S Kar, P Mishra, A These, C Kupfer… - ACS materials …, 2021 - ACS Publications
With rapid progress in the deployment of metal halide perovskites in various device
applications such as solar cells, light-emitting devices, field-effect transistors …

[LIBRO][B] Conical intersections: electronic structure, dynamics & spectroscopy

W Domcke, H Koppel, DR Yarkony - 2004 - books.google.com
It is widely recognized nowadays that conical intersections of molecular potential-energy
surfaces play a key mechanistic role in the spectroscopy of polyatomic molecules …

Distortion/interaction energy control of 1, 3-dipolar cycloaddition reactivity

DH Ess, KN Houk - Journal of the American Chemical Society, 2007 - ACS Publications
Computations of activation barriers and reaction energies for 1, 3-dipolar cycloadditions by a
high-accuracy quantum mechanical method (CBS-QB3) now reveal previously …

Pseudo-Jahn–Teller Effect A Two-State Paradigm in Formation, Deformation, and Transformation of Molecular Systems and Solids

IB Bersuker - Chemical Reviews, 2013 - ACS Publications
The pseudo-Jahn− Teller effect is the only source of instability and distortions of high-
symmetry configurations of polyatomic systems in nondegenerate states, and it contributes …

Structure and properties of functional oxide thin films: insights from electronic‐structure calculations

JM Rondinelli, NA Spaldin - Advanced materials, 2011 - Wiley Online Library
The confluence of state‐of‐the‐art electronic‐structure computations and modern synthetic
materials growth techniques is proving indispensable in the search for and discovery of new …

Novel two-dimensional semiconductor SnP 3: high stability, tunable bandgaps and high carrier mobility explored using first-principles calculations

S Sun, F Meng, H Wang, H Wang, Y Ni - Journal of Materials Chemistry …, 2018 - pubs.rsc.org
We propose a novel two-dimensional crystal based on layered bulk metallic SnP3 using first-
principles calculations. The obtained low cleavage energy of monolayer and bilayer SnP3 …