Organic peroxides in aerosol: key reactive intermediates for multiphase processes in the atmosphere
Organic peroxides (POs) are organic molecules with one or more peroxide (− O–O−)
functional groups. POs are commonly regarded as chemically labile termination products …
functional groups. POs are commonly regarded as chemically labile termination products …
Recent advances in understanding secondary organic aerosol: Implications for global climate forcing
Anthropogenic emissions and land use changes have modified atmospheric aerosol
concentrations and size distributions over time. Understanding preindustrial conditions and …
concentrations and size distributions over time. Understanding preindustrial conditions and …
Particle-phase accretion forms dimer esters in pinene secondary organic aerosol
CM Kenseth, NJ Hafeman, SP Rezgui, J Chen… - Science, 2023 - science.org
Secondary organic aerosol (SOA) is ubiquitous in the atmosphere and plays a pivotal role in
climate, air quality, and health. The production of low-volatility dimeric compounds through …
climate, air quality, and health. The production of low-volatility dimeric compounds through …
Large gas-phase source of esters and other accretion products in the atmosphere
Dimeric accretion products have been observed both in atmospheric aerosol particles and in
the gas phase. With their low volatilities, they are key contributors to the formation of new …
the gas phase. With their low volatilities, they are key contributors to the formation of new …
Radical chemistry in oxidation flow reactors for atmospheric chemistry research
Z Peng, JL Jimenez - Chemical Society Reviews, 2020 - pubs.rsc.org
Environmental chambers have been playing a vital role in atmospheric chemistry research
for seven decades. In last decade, oxidation flow reactors (OFR) have emerged as a …
for seven decades. In last decade, oxidation flow reactors (OFR) have emerged as a …
On the fate of oxygenated organic molecules in atmospheric aerosol particles
V Pospisilova, FD Lopez-Hilfiker, DM Bell… - Science …, 2020 - science.org
Highly oxygenated organic molecules (HOMs) are formed from the oxidation of biogenic and
anthropogenic gases and affect Earth's climate and air quality by their key role in particle …
anthropogenic gases and affect Earth's climate and air quality by their key role in particle …
Quantitative constraints on autoxidation and dimer formation from direct probing of monoterpene-derived peroxy radical chemistry
Organic peroxy radicals (RO2) are key intermediates in the atmospheric degradation of
organic matter and fuel combustion, but to date, few direct studies of specific RO2 in …
organic matter and fuel combustion, but to date, few direct studies of specific RO2 in …
Highly oxygenated multifunctional compounds in α-pinene secondary organic aerosol
Highly oxygenated multifunctional organic compounds (HOMs) originating from biogenic
emissions constitute a widespread source of organic aerosols in the pristine atmosphere …
emissions constitute a widespread source of organic aerosols in the pristine atmosphere …
Criegee intermediates beyond ozonolysis: Synthetic and mechanistic insights
Z Hassan, M Stahlberger… - Angewandte Chemie …, 2021 - Wiley Online Library
After more than 70 years since their discovery, Criegee intermediates (CIs) are back at the
forefront of modern chemistry of short‐lived reactive intermediates. They play an important …
forefront of modern chemistry of short‐lived reactive intermediates. They play an important …
The effect of temperature and relative humidity on secondary organic aerosol formation from ozonolysis of Δ 3-carene
D Thomsen, EM Iversen, JT Skønager, Y Luo… - Environmental …, 2024 - pubs.rsc.org
This study investigates the effects of temperature and relative humidity (RH) on the formation
of secondary organic aerosol (SOA) from Δ3-carene, a prevalent monoterpene in boreal …
of secondary organic aerosol (SOA) from Δ3-carene, a prevalent monoterpene in boreal …