Determination of absolute configuration of chiral molecules using vibrational optical activity: a review

Y He, W Bo, RK Dukor, LA Nafie - Applied Spectroscopy, 2011 - opg.optica.org
Determination of the absolute handedness, known as absolute configuration (AC), of chiral
molecules is an important step in any field related to chirality, especially in the …

Absolute configurations of synthetic molecular scaffolds from vibrational CD spectroscopy

C Merten, TP Golub, NM Kreienborg - The Journal of organic …, 2019 - ACS Publications
Vibrational circular dichroism (VCD) spectroscopy is one of the most powerful techniques for
the determination of absolute configurations (AC), as it does not require any specific UV/vis …

Liquid chromatography enantioseparations of halogenated compounds on polysaccharide‐based chiral stationary phases: Role of halogen substituents in molecular …

P Peluso, V Mamane, S Cossu - Chirality, 2015 - Wiley Online Library
Halogenated chiral molecules have become important in several fields of science, industry,
and society as drugs, natural compounds, agrochemicals, environmental pollutants …

Stereoselective Halogenation of Integral Unsaturated C‐C Bonds in Chemically and Mechanically Robust Zr and Hf MOFs

RJ Marshall, SL Griffin, C Wilson… - Chemistry–A European …, 2016 - Wiley Online Library
Metal–organic frameworks (MOFs) containing ZrIV‐based secondary building units (SBUs),
as in the UiO‐66 series, are receiving widespread research interest due to their enhanced …

Regioselective Iodoazidation of Alkynes: Synthesis of α, α-Diazidoketones

N Okamoto, T Sueda, H Minami, Y Miwa… - Organic letters, 2015 - ACS Publications
Regioselective Iodoazidation of Alkynes: Synthesis of α,α-Diazidoketones | Organic Letters
ACS ACS Publications C&EN CAS Find my institution Log In Organic Letters ACS Publications …

Synergistic effect of palladium and copper catalysts: catalytic cyclizative dimerization of ortho-(1-alkynyl) benzamides leading to axially chiral 1, 3-butadienes.

B Yao, C Jaccoud, Q Wang, J Zhu - Chemistry (Weinheim an der …, 2012 - europepmc.org
Two is better than one: In the presence of Pd (OAc)(2) and Cu (OAc)(2), o-(1-alkynyl)
benzamides 1 were converted into bis-iminobenzoisofurans with an axially chiral 1, 3-diene …

Ligand-Free Iron-Catalyzed Carbon (sp2)–Carbon (sp2) Oxidative Homo-Coupling of Alkenyllithiums

Z Zhong, ZY Wang, SF Ni, L Dang, HK Lee… - Organic …, 2019 - ACS Publications
A new strategy was developed for the efficient synthesis of di-, tetra-, and hexa-substituted 1,
3-butadienes. This one-pot procedure involves lithium–iodine exchange to generate the …

Atropisomers of arylmaleimides: stereodynamics and absolute configuration

M Ambrogi, A Ciogli, M Mancinelli… - The Journal of …, 2013 - ACS Publications
4-Aryl-3-bromo-N-benzylmaleimides and 3, 4-biaryl-N-benzylmaleimides have been
synthesized by a modified Suzuki cross-coupling reaction from 3, 4-dibromo-N …

Strain‐Accelerated Formation of Chiral, Optically Active Buta‐1, 3‐dienes

M Chiu, BH Tchitchanov, D Zimmerli… - Angewandte Chemie …, 2015 - Wiley Online Library
Abstract The formal [2+ 2] cycloaddition–retroelectrocyclization (CA–RE) reactions between
tetracyanoethylene (TCNE) and strained, electron‐rich dibenzo‐fused cyclooctynes were …

Planar Chiral p,p′-Terphenyl-Based Cyclophanes with Remarkable Enantiomer Stability: Synthesis, Theoretical Investigations, and Complexation Studies

I Stroia, ME Moisă, A Pop, B Legrand… - The Journal of …, 2023 - ACS Publications
Design of conformationally stable compounds with planar chirality is a topic of great interest
mainly because of their potential applications as enantioselective ligands or other functional …