Vitreous and crystalline phosphate high level waste matrices: Present status and future challenges

A Bohre, K Avasthi, VI Pet'kov - Journal of Industrial and Engineering …, 2017 - Elsevier
Vitrification is currently the most effective process for immobilization of nuclear waste.
However, ubiquitous borosilicate glass is not suitable for immobilization of nuclear waste …

Inorganic waste forms for efficient immobilization of radionuclides

BK Singh, MA Hafeez, H Kim, S Hong… - ACS ES&T …, 2021 - ACS Publications
The immobilization of long-lived radionuclide wastes generated from nuclear power plants
(NPPs) during NPP operation, fuel reprocessing, and decommissioning of nuclear reactors …

Monazite as a promising long-term radioactive waste matrix: Benefits of high-structural flexibility and chemical durability.

N Dacheux, N Clavier, R Podor - American Mineralogist, 2013 - degruyter.com
ABSTRACT Monazite (Ln3+PO4) and related solid solutions are a well-known source of rare
earth elements on earth. They may also accommodate large amounts of thorium and …

Preparation and characterization of lanthanum–gadolinium monazites as ceramics for radioactive waste storage

O Terra, N Clavier, N Dacheux, R Podor - New journal of Chemistry, 2003 - pubs.rsc.org
Several La1− xGdxPO4 solid solutions were prepared in the monazite-or rhabdophane-type
structures for various x values using three methods of preparation (direct evaporation …

[HTML][HTML] Immobilisation of actinides in phosphate matrices

N Dacheux, N Clavier, AC Robisson, O Terra… - Comptes Rendus …, 2004 - Elsevier
In the field of the immobilisation of high-activity-level and long-life radwaste (HAVL) for a
deep underground repository, several phosphate matrices were already proposed as good …

New insights into phosphate based materials for the immobilisation of actinides

S Neumeier, Y Arinicheva, Y Ji, JM Heuser… - Radiochimica …, 2017 - degruyter.com
This paper focuses on major phosphate-based ceramic materials relevant for the
immobilisation of Pu, minor actinides, fission and activation products. Key points addressed …

Actinide solubility-controlling phases during the dissolution of phosphate ceramics

EDF de Kerdaniel, N Clavier, N Dacheux… - Journal of nuclear …, 2007 - Elsevier
Phosphate ceramics (britholites, monazite/brabantite solid solutions, thorium phosphate
diphosphate, ie β-TPD, and associated β-TPD/monazite composites) are often considered …

Influence of crystallization state and microstructure on the chemical durability of cerium–neodymium mixed oxides

L Claparede, N Clavier, N Dacheux, P Moisy… - Inorganic …, 2011 - ACS Publications
To underline the potential links between the crystallization state and the microstructure of
powdered cerium–neodymium oxides and their chemical durability, several CeIV1–x NdIII x …

Multiparametric dissolution of thorium–cerium dioxide solid solutions

L Claparede, N Clavier, N Dacheux, A Mesbah… - Inorganic …, 2011 - ACS Publications
The dissolution of Th1–x Ce x O2 solid solutions samples prepared by thermal conversion of
oxalate precursors was studied by varying independently several parameters (such as …

Dissolution of cerium (IV)–Lanthanide (III) oxides: comparative effect of chemical composition, temperature, and acidity

D Horlait, N Clavier, S Szenknect, N Dacheux… - Inorganic …, 2012 - ACS Publications
The dissolution of Ce1–x Ln x O2–x/2 solid solutions was undertaken in various acid media
in order to evaluate the effects of several physicochemical parameters such as chemical …