Metal–organic frameworks and covalent organic frameworks as disruptive membrane materials for energy-efficient gas separation

AA Knebel, J Caro - Nature Nanotechnology, 2022 - nature.com
In this Review we survey the molecular sieving behaviour of metal–organic framework
(MOF) and covalent organic framework (COF) membranes, which is different from that of …

Advances in metal–organic framework-based membranes

Y Cheng, SJ Datta, S Zhou, J Jia, O Shekhah… - Chemical Society …, 2022 - pubs.rsc.org
Membrane-based separations have garnered considerable attention owing to their high
energy efficiency, low capital cost, small carbon footprint, and continuous operation mode …

Rational design of mixed-matrix metal-organic framework membranes for molecular separations

SJ Datta, A Mayoral, N Murthy Srivatsa Bettahalli… - Science, 2022 - science.org
Conventional separation technologies to separate valuable commodities are energy
intensive, consuming 15% of the worldwide energy. Mixed-matrix membranes, combining …

MOF-based membranes for gas separations

Q Qian, PA Asinger, MJ Lee, G Han… - Chemical …, 2020 - ACS Publications
Metal–organic frameworks (MOFs) represent the largest known class of porous crystalline
materials ever synthesized. Their narrow pore windows and nearly unlimited structural and …

Tuning MOF/polymer interfacial pore geometry in mixed matrix membrane for upgrading CO2 separation performance

A Ozcan, D Fan, SJ Datta, A Diaz-Marquez… - Science …, 2024 - science.org
The current paradigm considers the control of the MOF/polymer interface mostly for
achieving a good compatibility between the two components to ensure the fabrication of …

MOF-polymer hybrid materials: from simple composites to tailored architectures

M Kalaj, KC Bentz, S Ayala Jr, JM Palomba… - Chemical …, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are inherently crystalline, brittle porous solids.
Conversely, polymers are flexible, malleable, and processable solids that are used for a …

Boosting membrane carbon capture via multifaceted polyphenol-mediated soldering

B Zhu, S He, Y Yang, S Li, CH Lau, S Liu… - Nature …, 2023 - nature.com
Advances in membrane technologies are significant for mitigating global climate change
because of their low cost and easy operation. Although mixed-matrix membranes (MMMs) …

50th Anniversary Perspective: Polymers and Mixed Matrix Membranes for Gas and Vapor Separation: A Review and Prospective Opportunities

M Galizia, WS Chi, ZP Smith, TC Merkel… - …, 2017 - ACS Publications
Membrane gas separation is a mature and expanding technology. However, the availability
of better membrane materials would promote faster growth. In this Perspective we analyze …

CO2 Capture and Separations Using MOFs: Computational and Experimental Studies

J Yu, LH **e, JR Li, Y Ma, JM Seminario… - Chemical …, 2017 - ACS Publications
This Review focuses on research oriented toward elucidation of the various aspects that
determine adsorption of CO2 in metal–organic frameworks and its separation from gas …

Hybridization of MOFs and polymers

T Kitao, Y Zhang, S Kitagawa, B Wang… - Chemical Society …, 2017 - pubs.rsc.org
Metal–organic frameworks (MOFs) have received much attention because of their attractive
properties. They show great potential applications in many fields. An emerging trend in MOF …