Quantum crystallography

S Grabowsky, A Genoni, HB Bürgi - Chemical science, 2017 - pubs.rsc.org
Approximate wavefunctions can be improved by constraining them to reproduce
observations derived from diffraction and scattering experiments. Conversely, charge …

Quantum crystallography: Current developments and future perspectives

A Genoni, L Bučinský, N Claiser… - … A European Journal, 2018 - Wiley Online Library
Crystallography and quantum mechanics have always been tightly connected because
reliable quantum mechanical models are needed to determine crystal structures. Due to this …

Quantum chemical methods in charge density studies from X-ray diffraction data

AA Korlyukov, YV Nelyubina - Russian Chemical Reviews, 2019 - iopscience.iop.org
Single-crystal X-ray diffraction studies are among the best experimental methods for
elucidating the structure of chemical compounds. Recently, their focus has been shifted …

[HTML][HTML] The effects of experimentally obtained electron correlation and polarization on electron densities and exchange-correlation potentials

E Hupf, F Kleemiss, T Borrmann, R Pal… - The Journal of …, 2023 - pubs.aip.org
In X-ray constrained wavefunction (XCW) fitting, external information, such as electron
correlation and polarization, is included into a single-determinantal isolated-molecule …

[PDF][PDF] Hirshfeld atom like refinement with alternative electron density partitions

ML Chodkiewicz, M Woińska, K Woźniak - IUCrJ, 2020 - journals.iucr.org
Hirshfeld atom refinement is one of the most successful methods for the accurate
determination of structural parameters for hydrogen atoms from X-ray diffraction data. This …

Post-Hartree-Fock methods for Hirshfeld atom refinement: are they necessary? Investigation of a strongly hydrogen-bonded molecular crystal

EK Wieduwilt, G Macetti, LA Malaspina… - Journal of Molecular …, 2020 - Elsevier
Hirshfeld atom refinement (HAR) is a method for refining X-ray crystal structures that is able
to provide bond lengths involving hydrogen atoms in statistical agreement with those …

[PDF][PDF] Enhancing hydrogen positions in X-ray structures of transition metal hydride complexes with dynamic quantum crystallography

M Woińska, AA Hoser, ML Chodkiewicz, K Woźniak - IUCrJ, 2024 - journals.iucr.org
Hirshfeld atom refinement (HAR) is a method which enables the user to obtain more
accurate positions of hydrogen atoms bonded to light chemical elements using X-ray data …

Experimental X-ray Charge-Density Studies─A Suitable Probe for Superconductivity? A Case Study on MgB2

J Langmann, H Kepenci, G Eickerling… - The Journal of …, 2022 - ACS Publications
Case studies of 1T-TiSe2 and YBa2Cu3O7− δ have demonstrated that X-ray diffraction
(XRD) studies can be used to trace even subtle structural phase transitions which are …

Accurate Bond Lengths to Hydrogen Atoms from Single‐Crystal X‐ray Diffraction by Including Estimated Hydrogen ADPs and Comparison to Neutron and QM/MM …

B Dittrich, J Lübben, S Mebs, A Wagner… - … A European Journal, 2017 - Wiley Online Library
Amino acid structures are an ideal test set for method‐development studies in
crystallography. High‐resolution X‐ray diffraction data for eight previously studied …

Understanding Hygroscopicity of Theophylline via a Novel Cocrystal Polymorph: A Charge Density Study

SA Stanton, JJ Du, F Lai, G Stanton… - The Journal of …, 2021 - ACS Publications
The charge density distribution in a novel cocrystal (1) complex of 1, 3-dimethylxanthine
(theophylline) and propanedioic acid (malonic acid) has been determined. The molecules …