Mixed‐valence compounds with the iso‐cyanidometal‐ligand bridge in different oxidation
states are used as models for the investigation of the electron‐transfer process. We …

The Class II–III mixed-valence species have attracted great attention because of the
borderline behavior in the Class II to Class III transition. To further investigate those species …

The NIR and IR spectroscopic properties of the cyanide‐bridged complex, trans‐[Ru (dmap)
4 {(μ‐CN) Ru (py) 4Cl} 2] 3+(py= pyridine, dmap= 4‐dimethylaminopyridine) provide strong …

A series of trimetallic cyanidometal-bridged compounds with the formula [CpMexFe–NC–Ru–
CN–FeCpMex] n+, Nn+ (n= 2, 3 and 4; N= 1, x= 0; N= 2, x= 1; N= 3, x= 3; N= 4, x= 4; N= 5, x …

The two stable pairs of trimetallic compounds trans‐[Cp*(dppe) Ru (μ‐NC) Ru (dmap) 4 (μ‐
CN) Ru (dppe) Cp*][PF6] n (1 [PF6] n, n= 2, 3; Cp*= 1, 2, 3, 4, 5 …

Details of the reaction mechanism for the Ru–PNN pincer complex catalyzed amidation from
an alcohol and an amine proposed by Milstein et al. was elucidated using M06 density …

The selective hydrogenation of nitroarenes to N-arylhydroxylamines is an important
synthetic process in the chemical industry. It is commonly accomplished by using …

Investigations on mixed-valent complexes in the Class II/Class III frontier have been a
particularly interesting issue due to their special electron delocalization. In this work, a pair …

In this work, we report the evolution of the properties of the inter-valence charge transfer
(IVCT) transition in a family of cyanide-bridged ruthenium polypyridines of general formula …

To investigate the effect of metal-to-metal charge transfer (MMCT) in the complexes of
cyanidometal-bridges, we synthesized and fully characterized a series of trimetallic …