Iron and manganese oxo complexes, oxo wall and beyond
High-valent metal–oxo species with multiply-bonded M–O groups have been proposed as
key intermediates in many biological and abiological catalytic oxidation reactions. These …
key intermediates in many biological and abiological catalytic oxidation reactions. These …
Bioinspired Nonheme Iron Catalysts for C–H and C C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants
WN Oloo, L Que Jr - Accounts of chemical research, 2015 - ACS Publications
Conspectus Recent efforts to design synthetic iron catalysts for the selective and efficient
oxidation of C–H and C C bonds have been inspired by a versatile family of nonheme iron …
oxidation of C–H and C C bonds have been inspired by a versatile family of nonheme iron …
Trap** a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C H Bonds with Stereoretention
An unprecedentedly reactive iron species (2) has been generated by reaction of excess
peracetic acid with a mononuclear iron complex [FeII (CF3SO3) 2 (PyNMe3)](1) at cryogenic …
peracetic acid with a mononuclear iron complex [FeII (CF3SO3) 2 (PyNMe3)](1) at cryogenic …
Artificial nonheme iron and manganese oxygenases for enantioselective olefin epoxidation and alkane hydroxylation reactions
J Chen, Z Jiang, S Fukuzumi, W Nam… - Coordination Chemistry …, 2020 - Elsevier
The development of sustainable enantioselective olefin epoxidation and alkane oxidation
reactions under environmentally friendly conditions is an ultimate goal that has long been …
reactions under environmentally friendly conditions is an ultimate goal that has long been …
Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations
The selective oxidation of hydrocarbons is a challenging reaction for synthetic chemists, but
common in nature. Iron oxygenases activate the O–O bond of dioxygen to perform oxidation …
common in nature. Iron oxygenases activate the O–O bond of dioxygen to perform oxidation …
Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives
Iron coordination complexes with nitrogen and oxygen donor ligands have long since been
known to react with peroxides producing powerful oxidizing species. These compounds can …
known to react with peroxides producing powerful oxidizing species. These compounds can …
Biomimetic metal-oxidant adducts as active oxidants in oxidation reactions
M Guo, YM Lee, S Fukuzumi, W Nam - Coordination Chemistry Reviews, 2021 - Elsevier
Catalytic oxidation reactions are pivotal transformations in living creatures and chemical
industries, in which metal-oxygen intermediates, including high-valent metal-oxo species …
industries, in which metal-oxygen intermediates, including high-valent metal-oxo species …
Charged droplet-driven fast formation of nickel–iron (oxy) hydroxides with rich oxygen defects for boosting overall water splitting
J Dong, Y Wang, Q Jiang, ZA Nan, FR Fan… - Journal of Materials …, 2021 - pubs.rsc.org
NiFe (oxy) hydroxides (NiFeOOH) are considered as one of the most efficient
electrocatalysts for water splitting. Although several strategies recently have been …
electrocatalysts for water splitting. Although several strategies recently have been …
Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV–Oxo Intermediate
The reaction of [(PyNMe3) FeII (CF3SO3) 2], 1, with excess peracetic acid at− 40° C
generates a highly reactive intermediate, 2b (PAA), that has the fastest rate to date for …
generates a highly reactive intermediate, 2b (PAA), that has the fastest rate to date for …
Speciation in iron epoxidation catalysis: A perspective on the discovery and role of non-heme iron (III)-hydroperoxo species in iron-catalyzed oxidation reactions
SM Hölzl, PJ Altmann, JW Kück, FE Kühn - Coordination Chemistry …, 2017 - Elsevier
Oxidation reactions catalyzed by enzymes with central iron atoms are essential to life. The
nature of these systems has evoked great interest to understand and model their reactivity …
nature of these systems has evoked great interest to understand and model their reactivity …