Among the d10 coinage metal complexes, cyclic trinuclear complexes (CTCs) or trinuclear
metallocycles with intratrimer metal–metal interactions are fascinating and important metal …

Macrocyclic copper (I) and silver (I) pyrazolates represent an important class of coordination
compounds used in numerous fundamental areas, such as acid-base chemistry …

Luminescence mechanochromism of the well-known Cu3Pz3-type (Pz= pyrazolate)
complexes is reported here, which is unusual for this family. Two types of new Cu3Pz3 …

Syntheses, structural, and photoluminescence properties of {[4-X-3, 5-(CF3) 2Pz] M} 3 (X= Cl
or Br, M= Cu or Ag) containing a heavier halide at the pyrazolyl ring 4-positions are reported …

Straightforward practical synthetic approaches to 3, 4-bis-and 3, 4, 5-tris (trifluoromethyl)
pyrazoles have been developed. The key step of the both syntheses is a transformation of …

Almost equal molecular sizes of diiodoacetylene (C 2 I 2) and the [Br 3]− anion result in
isomorphic neutral cocrystal (DMFc–C 2 I 2) and [DMFc]+ Br 3− salt. This isomorphic pair of …

A macrocyclic host molecule possessing a nanocavity with two AgI centers for guest binding
and four anthracene walls has been developed. This dimetal-macrocycle forms stable …

The trinuclear copper (I) pyrazolate {[3, 5-(CF3) 2Pz] Cu} 3 forms η2-copper/alkyne triple
bond coordinated structures in the presence of acetylenes. There is no coordination of …

The interaction of copper (I) and silver (I) macrocyclic pyrazolates with aromatic ligands of
ruthenium sandwiches (Cp* RuInd, CpRuInd, and Ind2Ru) in solution is shown for the first …

This work describes the reaction of a cyclic trinuclear complex,{[3, 5-(CF3) 2Pz] Cu} 3, with
internal alkynes to construct di-and tetranuclear copper (I) complexes with short cuprophilic …