Strong metal–support interaction in heterogeneous catalysts

Z Luo, G Zhao, H Pan, W Sun - Advanced Energy Materials, 2022 - Wiley Online Library
Strong metal–support interaction (SMSI) in supported metal catalysts, typically accompanied
by the formation of encapsulation layers over metal nanoparticles, has drawn intense …

Engineering heterogeneous catalysis with strong metal–support interactions: characterization, theory and manipulation

T Pu, W Zhang, M Zhu - Angewandte Chemie International …, 2023 - Wiley Online Library
Strong metal–support interactions (SMSI) represent a classic yet fast‐growing area in
catalysis research. The SMSI phenomenon results in the encapsulation and stabilization of …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Interfacial compatibility critically controls Ru/TiO2 metal-support interaction modes in CO2 hydrogenation

J Zhou, Z Gao, G **ang, T Zhai, Z Liu, W Zhao… - Nature …, 2022 - nature.com
Supports can widely affect or even dominate the catalytic activity, selectivity, and stability of
metal nanoparticles through various metal-support interactions (MSIs). However, underlying …

Ammonia as hydrogen carrier: Advances in ammonia decomposition catalysts for promising hydrogen production

S Sun, Q Jiang, D Zhao, T Cao, H Sha, C Zhang… - … and Sustainable Energy …, 2022 - Elsevier
On-site ammonia decomposition has been considered as a potential candidate to alleviate
the challenges of hydrogen storage and transportation by utilizing NH 3 (with a high …

Structure Sensitivity of Au‐TiO2 Strong Metal–Support Interactions

Y Zhang, JX Liu, K Qian, A Jia, D Li… - Angewandte Chemie …, 2021 - Wiley Online Library
Strong metal–support interactions (SMSI) is an important concept in heterogeneous
catalysis. Herein, we demonstrate that the Au‐TiO2 SMSI of Au/TiO2 catalysts sensitively …

Photo-thermo semi-hydrogenation of acetylene on Pd1/TiO2 single-atom catalyst

Y Guo, Y Huang, B Zeng, B Han, M Akri, M Shi… - Nature …, 2022 - nature.com
Semi-hydrogenation of acetylene in excess ethylene is a key industrial process for ethylene
purification. Supported Pd catalysts have attracted most attention due to their superior …

Graphitic carbon nitride-based nanostructures as emergent catalysts for carbon monoxide (CO) oxidation

K Eid, A Gamal, AM Abdullah - Green Chemistry, 2023 - pubs.rsc.org
Pristine graphitic carbon nitride-based catalysts (g-C3N4) are promising in multidisciplinary
applications due to their unique physicochemical properties, metal-free nature, optical …

Atomically thick oxide overcoating stimulates low-temperature reactive metal–support interactions for enhanced catalysis

X Liu, Q Gu, Y Zhang, X Xu, H Wang… - Journal of the …, 2023 - ACS Publications
Reactive metal–support interactions (RMSIs) induce the formation of bimetallic alloys and
offer an effective way to tune the electronic and geometric properties of metal sites for …

Electronic metal–support interaction triggering interfacial charge polarization over CuPd/N‐doped‐C nanohybrids drives selectively electrocatalytic conversion of …

Y Xu, K Shi, T Ren, H Yu, K Deng, X Wang, Z Wang… - Small, 2022 - Wiley Online Library
Selective electrocatalytic nitrate‐to‐ammonia conversion holds significant potential in
treatment of nitrate wastewater and simultaneously produces high‐value‐added ammonia …