Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Non-noble metal-based molecular complexes for CO2 reduction: From the ligand design perspective

DC Liu, DC Zhong, TB Lu - EnergyChem, 2020 - Elsevier
Molecular catalysts for electrochemical and photochemical CO 2 reduction have developed
rapidly during the past two decades. Using non-noble metal (Ni, Co, Mn, Fe, and Cu) …

A Mesoionic Carbene–Pyridine Bidentate Ligand That Improves Stability in Electrocatalytic CO2 Reduction by a Molecular Manganese Catalyst

T Scherpf, CR Carr, LJ Donnelly… - Inorganic …, 2022 - ACS Publications
Tricarbonyl Group 7 complexes have a longstanding history as efficacious CO2
electroreduction catalysts. Typically, these complexes feature an auxiliary 2, 2′-bipyridine …

Electrocatalyst decomposition pathways: torsional strain in a second sphere proton relay shuts off CO 2 RR in a Re (2, 2′-bipyridyl)(CO) 3 X type electrocatalyst

ZS Dubrawski, CY Chang, CR Carr, BS Gelfand… - Dalton …, 2022 - pubs.rsc.org
Group 7 tris (carbonyl) bipyridine complexes have been well explored as important CO2
reduction reaction (CO2RR) electrocatalysts and now represent an excellent platform for …

Carbon Dioxide Electroreduction and Formic Acid Oxidation by Formal Nickel (I) Complexes of Di‐isopropylphenyl Bis‐iminoacenaphthene

VV Khrizanforova, RR Fayzullin… - … A European Journal, 2024 - Wiley Online Library
Processing CO2 into value–added chemicals and fuels stands as one of the most crucial
tasks in addressing the global challenge of the greenhouse effect. In this study, we focused …

Übergangsmetallkomplexe als Katalysatoren für die elektrische Umwandlung von CO2–eine metallorganische Perspektive

NW Kinzel, C Werlé, W Leitner - Angewandte Chemie, 2021 - Wiley Online Library
Abstract Die elektrokatalytische Umwandlung von Kohlendioxid ist in der CO2‐Nutzung seit
langem von Interesse. Während sich viele Studien auf den direkten Elektronentransfer vom …

Synthesis, structure, and physicochemical properties of molecular rhenium cluster complexes with 4-phenylpyridine molecules as terminal ligands

AA Ulantikov, YM Gayfulin, TS Sukhikh… - Journal of Structural …, 2021 - Springer
Four novel rhenium cluster complexes with the general formula trans-[Re6 Q 8 (ppy) 4 X 2]·
n (ppy)(Q= S, Se; X= Cl, Br; ppy= 4-phenylpyridine) are obtained by the interaction of salts …

A chelate like no other: exploring the synthesis, coordination chemistry and applications of imidoyl amidine frameworks

AA Kitos, N Mavragani, M Murugesu, JL Brusso - Materials Advances, 2020 - pubs.rsc.org
Since the remarkable work by Werner, the design and use of chelating ligands have played
an essential part in coordination chemistry. While ligands such as 2, 4-pentanedione (acac) …

[HTML][HTML] A Series of Zinc Mononuclear Complexes with Imidoyl Amidine Ligands: Syntheses, Crystal Structures, and Photoluminescence Properties

MR Nijhuis, Z Yamba, E Novikov, MS Fonari… - Chemistry, 2024 - mdpi.com
Three amidine-based ligands were used in the crystal design of a series of mononuclear Zn
(II) complexes. Interaction of zinc chloride, ZnCl2, with N-2-pyridylimidoyl-2-pyridylamidine …

[PDF][PDF] Development and Mechanistic Analysis of Novel CO2 Reduction Electrocatalysts

ZS Dubrawski - Development, 2023 - prism.ucalgary.ca
The ever-growing anthropogenic concentrations of CO2 in our atmosphere has led to an
entire industry centered around Carbon Capture and Utilization (CCU). One central pillar of …