Biocatalysis has revolutionized chemical synthesis, providing sustainable methods for
preparing various organic molecules. In enzyme-mediated organic synthesis, most reactions …

In recent years, powerful genetic code reprogramming methods have emerged that allow
new functional components to be embedded into proteins as noncanonical amino acid …

Conspectus Harnessing biocatalysts for novel abiological transformations is a longstanding
goal of synthetic chemistry. Combining the merits of biocatalysis and photocatalysis allows …

Biocatalysis has become an important component of modern organic chemistry, presenting
an efficient and environmentally friendly approach to synthetic transformations. Advances in …

Photocatalysis is a versatile and rapidly develo** field with applications spanning artificial
photosynthesis, photo-biocatalysis, photoredox catalysis in solution or supramolecular …

Artificial photoenzymes with novel catalytic modes not found in nature are in high demand;
yet, they also present significant challenges in the field of biocatalysis. In this study, a …

Cerium photoredox catalysis has emerged as a powerful strategy to activate molecules
under mild conditions. Radical intermediates are formed using visible light and simple …

Repurposing enzymes to catalyze non‐natural asymmetric transformations that are difficult
to achieve using traditional chemical methods is of significant importance. Although radical …

The development of artificial metalloenzymes (ArMs) aims to expand the capabilities of
enzymatic catalysis, most notably towards new reaction mechanisms. Frequently, ArMs …

Efficient and environmentally friendly conversion of light energy for direct utilization in
chemical production has been a long-standing goal in enzyme design. Herein, we …