Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte
To date, copper is the only heterogeneous catalyst that has shown a propensity to produce
valuable hydrocarbons and alcohols, such as ethylene and ethanol, from electrochemical …
valuable hydrocarbons and alcohols, such as ethylene and ethanol, from electrochemical …
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
The electrocatalytic reduction of carbon dioxide is a promising approach for storing (excess)
renewable electricity as chemical energy in fuels. Here, we review recent advances and …
renewable electricity as chemical energy in fuels. Here, we review recent advances and …
Understanding the Roadmap for Electrochemical Reduction of CO2 to Multi-Carbon Oxygenates and Hydrocarbons on Copper-Based Catalysts
Electrochemical reduction of CO2 to high-energy-density oxygenates and hydrocarbons
beyond CO is important for long-term and large-scale renewable energy storage. However …
beyond CO is important for long-term and large-scale renewable energy storage. However …
Complementary Operando Spectroscopy identification of in-situ generated metastable charge-asymmetry Cu2-CuN3 clusters for CO2 reduction to ethanol
Copper-based materials can reliably convert carbon dioxide into multi-carbon products but
they suffer from poor activity and product selectivity. The atomic structure-activity relationship …
they suffer from poor activity and product selectivity. The atomic structure-activity relationship …
Surface and interface control in nanoparticle catalysis
The surface and interfaces of heterogeneous catalysts are essential to their performance as
they are often considered to be active sites for catalytic reactions. With the development of …
they are often considered to be active sites for catalytic reactions. With the development of …
Interfacial Electrolyte Effects on Electrocatalytic CO2 Reduction
Electrocatalytic CO2 reduction (CO2RR), powered by renewable energy, has great potential
in decreasing the concentration of CO2 in the atmosphere, as well as producing high value …
in decreasing the concentration of CO2 in the atmosphere, as well as producing high value …
Microkinetic modeling: a tool for rational catalyst design
AH Motagamwala, JA Dumesic - Chemical Reviews, 2020 - ACS Publications
The design of heterogeneous catalysts relies on understanding the fundamental surface
kinetics that controls catalyst performance, and microkinetic modeling is a tool that can help …
kinetics that controls catalyst performance, and microkinetic modeling is a tool that can help …
In Situ Infrared Spectroscopic Evidence of Enhanced Electrochemical CO2 Reduction and C–C Coupling on Oxide-Derived Copper
The reaction mechanism of CO2 electroreduction on oxide-derived copper has not yet been
unraveled even though high C2+ Faradaic efficiencies are commonly observed on these …
unraveled even though high C2+ Faradaic efficiencies are commonly observed on these …
Operando time-resolved X-ray absorption spectroscopy reveals the chemical nature enabling highly selective CO2 reduction
Copper electrocatalysts have been shown to selectively reduce carbon dioxide to
hydrocarbons. Nevertheless, the absence of a systematic study based on time-resolved …
hydrocarbons. Nevertheless, the absence of a systematic study based on time-resolved …