Reactivity of surface species in heterogeneous catalysts probed by in situ X-ray absorption techniques

S Bordiga, E Groppo, G Agostini… - Chemical …, 2013 - ACS Publications
Starting from the late seventies, the progressively increased availability of synchrotron light
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …

[HTML][HTML] A Systematic Review of Amino Acid-Based Adsorbents for CO2 Capture

NS Mohamed Hatta, MK Aroua, F Hussin, LT Gew - Energies, 2022 - mdpi.com
The rise of carbon dioxide (CO2) levels in the atmosphere emphasises the need for
improving the current carbon capture and storage (CCS) technology. A conventional …

Structure–activity relationships that identify metal–organic framework catalysts for methane activation

AS Rosen, JM Notestein, RQ Snurr - Acs Catalysis, 2019 - ACS Publications
In this work, we leverage advances in computational screening based on periodic density
functional theory (DFT) to study a diverse set of experimentally derived metal–organic …

Structural determination of a highly stable metal-organic framework with possible application to interim radioactive waste scavenging: Hf-UiO-66

S Jakobsen, D Gianolio, DS Wragg, MH Nilsen… - Physical Review B …, 2012 - APS
High-resolution synchrotron radiation x-ray powder diffraction (HR-XRPD) combined with Hf
L 3-edge extended x-ray absorption fine structure allowed us to determine the structure of a …

Insights into Adsorption of NH3 on HKUST-1 Metal–Organic Framework: A Multitechnique Approach

E Borfecchia, S Maurelli, D Gianolio… - The Journal of …, 2012 - ACS Publications
We report a careful characterization of the interaction of NH3 with the Cu (II) sites of the
[Cu2C4O8] paddle-wheel cornerstone of the HKUST-1 metallorganic framework, also known …

Reversible Capture and Release of Cl2 and Br2 with a Redox-Active Metal–Organic Framework

Y Tulchinsky, CH Hendon… - Journal of the …, 2017 - ACS Publications
Extreme toxicity, corrosiveness, and volatility pose serious challenges for the safe storage
and transportation of elemental chlorine and bromine, which play critical roles in the …

Determination of the electronic and structural configuration of coordination compounds by synchrotron-radiation techniques

C Garino, E Borfecchia, R Gobetto… - Coordination Chemistry …, 2014 - Elsevier
In this review we provide an overview of the potential of synchrotron radiation techniques to
understand the structural and electronic properties of coordination compounds. Besides the …

Benzothiazolium-functionalized NU-1000: a versatile material for carbon dioxide adsorption and cyanide luminescence sensing

L Luconi, G Mercuri, T Islamoglu, A Fermi… - Journal of Materials …, 2020 - pubs.rsc.org
A tailor-made benzothiazolium bromide salt functionality (BzTz) is introduced via solvent-
assisted ligand incorporation (SALI) into the mesoporous Zr-based metal–organic …

Temperature-dependent nitrous oxide/carbon dioxide preferential adsorption in a thiazolium-functionalized NU-1000 metal–organic framework

G Mercuri, M Moroni, S Galli, G Tuci… - … Applied Materials & …, 2021 - ACS Publications
Solvent-assisted ligand incorporation (SALI) of the ditopic linker 5-carboxy-3-(4-
carboxybenzyl) thiazolium bromide [(H 2 PhTz) Br] into the zirconium metal–organic …

[HTML][HTML] Step-by-Step Growth of HKUST-1 on Functionalized TiO2 Surface: An Efficient Material for CO2 Capture and Solar Photoreduction

B Di Credico, M Redaelli, M Bellardita, M Calamante… - Catalysts, 2018 - mdpi.com
The present study reports on a simple preparation strategy of a hybrid catalyst, TiO2/HKUST-
1, containing TiO2 anatase nanoparticles (NPs) with tailored morphology and photocatalytic …