Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Spin crossover phenomena in Fe (ii) complexesDedicated to Professor FA Cotton on occasion of his 70th birthday.

P Gütlich, Y Garcia, HA Goodwin - Chemical Society Reviews, 2000 - pubs.rsc.org
The behaviour of spin crossover compounds is among the most striking and fascinating
shown by relatively simple molecular species. This review aims to draw attention to the …

The challenge of cyclic and acyclic Schiff bases and related derivatives

PA Vigato, S Tamburini - Coordination Chemistry Reviews, 2004 - Elsevier
The use of planar or tridimensional cyclic and acyclic Schiff bases, their polyamine
homologues and related derivatives, for the formation of mononuclear and especially …

Guest-dependent spin crossover in a nanoporous molecular framework material

GJ Halder, CJ Kepert, B Moubaraki, KS Murray… - Science, 2002 - science.org
The nanoporous metal-organic framework Fe2 (azpy) 4 (NCS) 4·(guest)(azpy is trans-4, 4′-
azopyridine) displays reversible uptake and release of guest molecules and contains …

Thermal, pressure and light switchable spin-crossover materials

JA Real, AB Gaspar, MC Muñoz - Dalton Transactions, 2005 - pubs.rsc.org
This article reviews the most relevant chemical and structural aspects that influence the spin-
crossover phenomenon (SCO). Special attention is focussed on the recent development of …

Polymorphism in spin-crossover systems

J Tao, RJ Wei, RB Huang, LS Zheng - Chemical Society Reviews, 2012 - pubs.rsc.org
The occurrence of spin-crossover (SCO) highly depends on external influences, ie
temperature, pressure, light irradiation or magnetic field, this electronic switching …

Multifunctionality in spin crossover materials

AB Gaspar, V Ksenofontov, M Seredyuk… - Coordination Chemistry …, 2005 - Elsevier
One of the most important trends in the spin crossover (SCO) field is focused on the
synthesis of new molecule-based functional materials in which the SCO properties may be …

Cooperativity in spin crossover systems: Memory, magnetism and microporosity

KS Murray, CJ Kepert - Spin Crossover in Transition Metal Compounds I, 2004 - Springer
This review deals with spin crossover effects in small polynuclear clusters, particularly
dinuclear species, and in extended network molecular materials, some of which have …

Cobalt (II) complexes of pyridazine or triazole containing ligands: spin-state control

U Beckmann, S Brooker - Coordination chemistry reviews, 2003 - Elsevier
Structurally characterised cobalt (II) complexes containing pyridazine, triazole or triazolate
ligands are the subject of this review. Firstly a brief introduction to Schiff-base macrocyclic …

Reversible switching of a cobalt complex by thermal, pressure, and electrochemical stimuli: abrupt, complete, hysteretic spin crossover

MG Cowan, J Olguín, S Narayanaswamy… - Journal of the …, 2012 - ACS Publications
Triply switchable [CoII (dpzca) 2] shows an abrupt, reversible, and hysteretic spin crossover
(T 1/2↓= 168 K, T 1/2↑= 179 K, and Δ T 1/2= 11 K) between the high-spin (HS) and low …