Recent progress in alkynylation with hypervalent iodine reagents
Although alkynes are one of the smallest functional groups, they are among the most
versatile building blocks for organic chemistry, with applications ranging from biochemistry …
versatile building blocks for organic chemistry, with applications ranging from biochemistry …
Recent Synthetic Applications of Hypervalent Iodine Reagents. A Review in Three Installments: Installment II
M Sihag, R Soni, N Rani, M Kinger… - Organic Preparations …, 2023 - Taylor & Francis
2-Arylbenzofurans are obtained by PIDA mediated oxidative cyclization of o-hydroxy
stilbenes in good yields (Scheme 99). Under mild conditions, PIDA acts as activator of the …
stilbenes in good yields (Scheme 99). Under mild conditions, PIDA acts as activator of the …
Asymmetric catalytic alkynylation of thiazolones and azlactones for synthesis of quaternary α-amino acid precursors
B Meng, Q Shi, Y Meng, J Chen, W Cao… - Organic & Biomolecular …, 2021 - pubs.rsc.org
Asymmetric alkynylation of thiazolones and azlactones with alkynylbenziodoxolones as the
electrophilic alkyne source catalyzed by thiourea phosphonium salt is described. By using …
electrophilic alkyne source catalyzed by thiourea phosphonium salt is described. By using …
Transition-Metal-Free Synthesis of Symmetrical 1, 4-Diarylsubstituted 1, 3-Diynes by Iodine-Mediated Decarboxylative Homocoupling of Arylpropiolic Acids
S Ghosh, SK Chattopadhyay - Tetrahedron Letters, 2022 - Elsevier
An efficient metal-free method for the synthesis of symmetrical 1, 3-diynes through iodine-
mediated decarboxylative homocoupling of aryl propiolic acids was developed. This iodine …
mediated decarboxylative homocoupling of aryl propiolic acids was developed. This iodine …
Iron-Catalyzed Cadiot–Chodkiewicz Coupling with High Selectivity in Water under Air
YA Liao, WS Peng, LJ Liu, TY Ye, JH Fu… - The Journal of …, 2022 - ACS Publications
An iron-based catalytic system was developed for the cross-coupling of 1-bromoalkynes with
terminal alkynes to selectively generate unsymmetrical 1, 3-butadiynes in water under air. It …
terminal alkynes to selectively generate unsymmetrical 1, 3-butadiynes in water under air. It …
[HTML][HTML] Dual-reactive single-chain polymer nanoparticles for orthogonal functionalization through active ester and click chemistry
Glucose has been extensively studied as a targeting ligand on nanoparticles for biomedical
nanoparticles. A promising nanocarrier platform are single-chain polymer nanoparticles …
nanoparticles. A promising nanocarrier platform are single-chain polymer nanoparticles …
Synthesis, Characterization of Spirocyclic λ3‐Iodanes and Their Application to Prepare 4,1‐Benzoxazepine‐2,5‐diones and 1,3‐Diynes
X Sun, XQ Guo, LM Chen… - Chemistry–A European …, 2021 - Wiley Online Library
Abstract Herein, a [3+ 2] cycloaddition of aza‐oxyallylic cations with ethynylbenziodoxolones
for synthesis of new λ3‐iodanes containing spirocyclic 4‐oxazolidinone has been …
for synthesis of new λ3‐iodanes containing spirocyclic 4‐oxazolidinone has been …
Synthesis of macrocyclic poly (glycidyl phenyl ether) with an inverted-dipole microstructure via ring closure of two-arm linear precursors obtained by initiation with t …
J Ochs, A Alegría, E González de San Román… - …, 2020 - ACS Publications
Dipolar microstructure is a property related to the orientation of dipole moments along a
polymer chain, which is dependent on how asymmetric monomers are oriented (ie, regio …
polymer chain, which is dependent on how asymmetric monomers are oriented (ie, regio …
Direct One‐Pot Construction of Diaryl Thioethers and 1,3‐Diynes through a Copper(I)‐Catalyzed Reaction of λ3‐Iodanes with Thiophenols
J Li, C Zhou, H Liang, XQ Guo… - European Journal of …, 2022 - Wiley Online Library
Herein, an efficient method for both aryl C (sp2)− S and C (sp)− C (sp) bond formation to
construct both diaryl thioethers and 1, 3‐diynes in excellent yield from spirocyclic λ3 …
construct both diaryl thioethers and 1, 3‐diynes in excellent yield from spirocyclic λ3 …
Deep Eutectic Solvent‐Mediated Oxidative Homocoupling of Terminal Alkynes to 1, 3‐Diynes under Mild Green Conditions
We prepared a commercially viable Deep Eutectic Solvent (DES) based on Choline
Chloride‐Urea‐copper acetate for the first time. It mediates the homocoupling of terminal …
Chloride‐Urea‐copper acetate for the first time. It mediates the homocoupling of terminal …