Recent progress in alkynylation with hypervalent iodine reagents

E Le Du, J Waser - Chemical Communications, 2023 - pubs.rsc.org
Although alkynes are one of the smallest functional groups, they are among the most
versatile building blocks for organic chemistry, with applications ranging from biochemistry …

Recent Synthetic Applications of Hypervalent Iodine Reagents. A Review in Three Installments: Installment II

M Sihag, R Soni, N Rani, M Kinger… - Organic Preparations …, 2023 - Taylor & Francis
2-Arylbenzofurans are obtained by PIDA mediated oxidative cyclization of o-hydroxy
stilbenes in good yields (Scheme 99). Under mild conditions, PIDA acts as activator of the …

Asymmetric catalytic alkynylation of thiazolones and azlactones for synthesis of quaternary α-amino acid precursors

B Meng, Q Shi, Y Meng, J Chen, W Cao… - Organic & Biomolecular …, 2021 - pubs.rsc.org
Asymmetric alkynylation of thiazolones and azlactones with alkynylbenziodoxolones as the
electrophilic alkyne source catalyzed by thiourea phosphonium salt is described. By using …

Transition-Metal-Free Synthesis of Symmetrical 1, 4-Diarylsubstituted 1, 3-Diynes by Iodine-Mediated Decarboxylative Homocoupling of Arylpropiolic Acids

S Ghosh, SK Chattopadhyay - Tetrahedron Letters, 2022 - Elsevier
An efficient metal-free method for the synthesis of symmetrical 1, 3-diynes through iodine-
mediated decarboxylative homocoupling of aryl propiolic acids was developed. This iodine …

Iron-Catalyzed Cadiot–Chodkiewicz Coupling with High Selectivity in Water under Air

YA Liao, WS Peng, LJ Liu, TY Ye, JH Fu… - The Journal of …, 2022 - ACS Publications
An iron-based catalytic system was developed for the cross-coupling of 1-bromoalkynes with
terminal alkynes to selectively generate unsymmetrical 1, 3-butadiynes in water under air. It …

[HTML][HTML] Dual-reactive single-chain polymer nanoparticles for orthogonal functionalization through active ester and click chemistry

JWD Paats, NM Hamelmann, JMJ Paulusse - Journal of Controlled …, 2024 - Elsevier
Glucose has been extensively studied as a targeting ligand on nanoparticles for biomedical
nanoparticles. A promising nanocarrier platform are single-chain polymer nanoparticles …

Synthesis, Characterization of Spirocyclic λ3‐Iodanes and Their Application to Prepare 4,1‐Benzoxazepine‐2,5‐diones and 1,3‐Diynes

X Sun, XQ Guo, LM Chen… - Chemistry–A European …, 2021 - Wiley Online Library
Abstract Herein, a [3+ 2] cycloaddition of aza‐oxyallylic cations with ethynylbenziodoxolones
for synthesis of new λ3‐iodanes containing spirocyclic 4‐oxazolidinone has been …

Synthesis of macrocyclic poly (glycidyl phenyl ether) with an inverted-dipole microstructure via ring closure of two-arm linear precursors obtained by initiation with t …

J Ochs, A Alegría, E González de San Román… - …, 2020 - ACS Publications
Dipolar microstructure is a property related to the orientation of dipole moments along a
polymer chain, which is dependent on how asymmetric monomers are oriented (ie, regio …

Direct One‐Pot Construction of Diaryl Thioethers and 1,3‐Diynes through a Copper(I)‐Catalyzed Reaction of λ3‐Iodanes with Thiophenols

J Li, C Zhou, H Liang, XQ Guo… - European Journal of …, 2022 - Wiley Online Library
Herein, an efficient method for both aryl C (sp2)− S and C (sp)− C (sp) bond formation to
construct both diaryl thioethers and 1, 3‐diynes in excellent yield from spirocyclic λ3 …

Deep Eutectic Solvent‐Mediated Oxidative Homocoupling of Terminal Alkynes to 1, 3‐Diynes under Mild Green Conditions

RS Bhise, PV Ghorpade, VR Mehta… - …, 2023 - Wiley Online Library
We prepared a commercially viable Deep Eutectic Solvent (DES) based on Choline
Chloride‐Urea‐copper acetate for the first time. It mediates the homocoupling of terminal …