Post-polymerization modification reactions of poly (glycidyl methacrylate) s

EM Muzammil, A Khan, MC Stuparu - RSC advances, 2017‏ - pubs.rsc.org
Post-polymerisation modification of poly (glycidyl methacrylate)(PGMA) through the
nucleophilic ring opening reactions of the pendent epoxide groups allows for the installation …

Adapting benzoxazine chemistry for unconventional applications

B Kiskan - Reactive and Functional Polymers, 2018‏ - Elsevier
Polybenzoxazines, as a kind of phenolics, are high performance thermosets with a range of
features and overcoming some drawbacks of resole and novolac type phenolics. Most of the …

Thiol‐epoxy “click” chemistry: Application in preparation and postpolymerization modification of polymers

MC Stuparu, A Khan - Journal of Polymer Science Part A …, 2016‏ - Wiley Online Library
Base‐catalyzed reaction between a thiol and an epoxide group is a simple fusion process
that leads to the formation of a β‐hydroxythio‐ether linkage. This reaction is efficient, regio …

A curing system of benzoxazine with amine: reactivity, reaction mechanism and material properties

JQ Sun, W Wei, YZ Xu, JH Qu, XD Liu, T Endo - RSC Advances, 2015‏ - pubs.rsc.org
Five commercially available amines: m-phenylenediamine (A1), m-xylylenediamine (A2),
isophorone diamine (A3), trimethylhexamethylenediamine (A4), and 4, 4′-diaminodiphenyl …

Externally stimulated click reactions for macromolecular syntheses

MA Tasdelen, B Kiskan, Y Yagci - Progress in Polymer Science, 2016‏ - Elsevier
Over the last decade, click chemistry reactions, that are fast, simple to use, easy to purify,
versatile, regiospecific, and give high product yields have gained significant importance for …

Homopolymer bifunctionalization through sequential thiol–epoxy and esterification reactions: an optimization, quantification, and structural elucidation study

I Gadwal, MC Stuparu, A Khan - Polymer Chemistry, 2015‏ - pubs.rsc.org
In this study, we probe various aspects of a post-polymerization double-modification strategy
involving sequential thiol–epoxy and esterification reactions for the preparation of dual …

Phenolic naphthoxazines as curing promoters for benzoxazines

G Kaya, B Kiskan, Y Yagci - Macromolecules, 2018‏ - ACS Publications
The effect of phenolic hydroxyl bearing naphthoxazines as catalysts for the ring-opening
polymerization (ROP) of simple 1, 3-benzoxazines was investigated. The latent catalytic role …

Curing of bisphenol A-aniline based benzoxazine using phenolic, amino and mercapto accelerators.

A Ručigaj, B Alič, M Krajnc… - Express Polymer …, 2015‏ - search.ebscohost.com
The curing of bisphenol A-aniline based benzoxazine was studied applying different
accelerators (4, 4"-thiodiphenol, o-dianisidine, 2-mercaptobenzimidazole and 4 …

Ammonium salt catalyzed ring-opening polymerization of 1, 3-benzoxazines

A Kocaarslan, B Kiskan, Y Yagci - Polymer, 2017‏ - Elsevier
The effect of amine HCl salts as catalysts on the ring-opening polymerization (ROP) of
simple 1, 3-benzoxazines was investigated. The catalyst effects on the structure of the final …

Direct Introduction of Cysteine Derivatives into the Chain End of Helical Poly (quinoline-2, 3-diylmethylene) s: Densely Packed Monolayers on Au Substrates

N Kanbayashi, S Odagaki, N Kobayakawa… - …, 2024‏ - ACS Publications
Highly reactive functional groups at polymer chain ends, integral for creating structurally
diverse functional polymers and composites, present challenges in their introduction both …