Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …

Visible-light photocatalysis and electrocatalysis are two powerful strategies for the promotion
of chemical reactions that have received tremendous attention in recent years. In contrast …

The enantioselective functionalization of ubiquitous C (sp 3)–H bonds is ideally suited for
the construction of three-dimensional chiral structures. However, organic molecules often …

Electrochemistry has recently gained increased attention as a versatile strategy for
achieving challenging transformations at the forefront of synthetic organic chemistry …

Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …

The asymmetric difunctionalization of alkenes, a method transforming readily accessible
alkenes into enantioenriched chiral structures of high value, has long been a focal point of …

The employment of light and/or electricity–alternatively to conventional thermal energy–
unlocks new reactivity paradigms as tools for chemical substrate activations. This leads to …

The development of efficient and sustainable methods for decarboxylative transformations is
of great importance due to the ease of availability and nontoxicity of carboxylic acids …

Synthetic photoelectrochemistry (PEC) is receiving increasing attention as a new frontier for
the generation and handling of reactive intermediates. PEC permits selective single …

Classical photochemistry requires nanosecond excited-state lifetimes for diffusion-controlled
reactions. Excited radicals with picosecond lifetimes have been implied by numerous …