Applications of halogen-atom transfer (XAT) for the generation of carbon radicals in synthetic photochemistry and photocatalysis
The halogen-atom transfer (XAT) is one of the most important and applied processes for the
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …
Rational design of photocatalysts for controlled polymerization: effect of structures on photocatalytic activities
Over the past decade, the use of photocatalysts (PCs) in controlled polymerization has
brought new opportunities in sophisticated macromolecular synthesis. However, the …
brought new opportunities in sophisticated macromolecular synthesis. However, the …
Light-controlled radical polymerization: mechanisms, methods, and applications
The use of light to mediate controlled radical polymerization has emerged as a powerful
strategy for rational polymer synthesis and advanced materials fabrication. This review …
strategy for rational polymer synthesis and advanced materials fabrication. This review …
Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …
recommended as reversible deactivation radical polymerization) is undoubtedly a …
Photoinduced electron transfer reactions for macromolecular syntheses
Photochemical reactions, particularly those involving photoinduced electron transfer
processes, establish a substantial contribution to the modern synthetic chemistry, and the …
processes, establish a substantial contribution to the modern synthetic chemistry, and the …
Photocatalysis in organic and polymer synthesis
This review, with over 600 references, summarizes the recent applications of photoredox
catalysis for organic transformation and polymer synthesis. Photoredox catalysts are metallo …
catalysis for organic transformation and polymer synthesis. Photoredox catalysts are metallo …
Photomediated controlled radical polymerization
Photomediated controlled radical polymerization is a versatile method to prepare, under
mild conditions, various well-defined polymers with complex architecture, such as block and …
mild conditions, various well-defined polymers with complex architecture, such as block and …
Toward green atom transfer radical polymerization: current status and future challenges
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …
Red-light-driven atom transfer radical polymerization for high-throughput polymer synthesis in open air
Photoinduced reversible-deactivation radical polymerization (photo-RDRP) techniques offer
exceptional control over polymerization, providing access to well-defined polymers and …
exceptional control over polymerization, providing access to well-defined polymers and …
Externally controlled atom transfer radical polymerization
Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …