Second and outer coordination sphere effects in nitrogenase, hydrogenase, formate dehydrogenase, and CO dehydrogenase

ST Stripp, BR Duffus, V Fourmond, C Léger… - Chemical …, 2022 - ACS Publications
Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …

Hydrogenase as the basis for green hydrogen production and utilization

H Ji, L Wan, Y Gao, P Du, W Li, H Luo, J Ning… - Journal of Energy …, 2023 - Elsevier
Hydrogenase is a paradigm of highly efficient biocatalyst for H 2 production and utilization
evolved in nature. A dilemma is that despite the high activity and efficiency expected for …

Selective hydrogenation of nitro compounds to amines by coupled redox reactions over a heterogeneous biocatalyst

D Sokolova, TC Lurshay, JS Rowbotham… - Nature …, 2024 - nature.com
Cleaner synthesis of amines remains a key challenge in organic chemistry because of their
prevalence in pharmaceuticals, agrochemicals and synthetic building blocks. Here, we …

Replacing a cysteine ligand by selenocysteine in a [NiFe]-hydrogenase unlocks hydrogen production activity and addresses the role of concerted proton-coupled …

RM Evans, N Krahn, J Weiss, KA Vincent… - Journal of the …, 2024 - ACS Publications
Hydrogenases catalyze hydrogen/proton interconversion that is normally electrochemically
reversible (having minimal overpotential requirement), a special property otherwise almost …

Molecular hydrogen metabolism: a widespread trait of pathogenic bacteria and protists

SL Benoit, RJ Maier, RG Sawers… - … and Molecular Biology …, 2020 - journals.asm.org
Pathogenic microorganisms use various mechanisms to conserve energy in host tissues
and environmental reservoirs. One widespread but often overlooked means of energy …

The value of enzymes in solar fuels research–efficient electrocatalysts through evolution

RM Evans, B Siritanaratkul, CF Megarity… - Chemical Society …, 2019 - pubs.rsc.org
The reasons for using enzymes as tools for solar fuels research are discussed. Many
oxidoreductases, including components of membrane-bound electron-transfer chains in …

Mechanisms of energy transduction by charge translocating membrane proteins

F Calisto, FM Sousa, FV Sena, PN Refojo… - Chemical …, 2021 - ACS Publications
Life relies on the constant exchange of different forms of energy, ie, on energy transduction.
Therefore, organisms have evolved in a way to be able to harvest the energy made …

Trace impurities in sodium phosphate influences the physiological activity of Escherichia coli in M9 minimal medium

Y Soma, S Tominaga, K Tokito, Y Imado, K Naka… - Scientific reports, 2023 - nature.com
In the field of applied microbiology, reproducibility and experimental variability are important
factors that influence both basic research as well as process development for industrial …

Develo** high-affinity, oxygen-insensitive [NiFe]-hydrogenases as biocatalysts for energy conversion

C Greening, A Kropp, K Vincent… - Biochemical Society …, 2023 - portlandpress.com
The splitting of hydrogen (H2) is an energy-yielding process, which is important for both
biological systems and as a means of providing green energy. In biology, this reaction is …

Aerobic Photocatalytic H2 Production by a [NiFe] Hydrogenase Engineered to Place a Silver Nanocluster in the Electron Relay

L Zhang, G Morello, SB Carr… - Journal of the American …, 2020 - ACS Publications
Hydrogenase-1 (Hyd-1) from E. coli poses a conundrum regarding the properties of
electrocatalytic reversibility and associated bidirectionality now established for many redox …