Elucidating solvation structures for rational design of multivalent electrolytes—a review
Fundamental molecular-level understanding of functional properties of liquid solutions
provides an important basis for designing optimized electrolytes for numerous applications …
provides an important basis for designing optimized electrolytes for numerous applications …
Insights into Anion‐Solvent Interactions to Boost Stable Operation of Ether‐Based Electrolytes in Pure‐SiOx||LiNi0.8Mn0.1Co0.1O2 Full Cells
Ether solvents with superior reductive stability promise excellent interphasial stability with
high‐capacity anodes while the limited oxidative resistance hinders their high‐voltage …
high‐capacity anodes while the limited oxidative resistance hinders their high‐voltage …
Enhanced Stability of the Carba-closo-dodecaborate Anion for High-Voltage Battery Electrolytes through Rational Design
Future energy applications rely on our ability to tune liquid intermolecular interactions and
achieve designer electrolytes with highly optimized properties. In this work, we demonstrate …
achieve designer electrolytes with highly optimized properties. In this work, we demonstrate …
Role of solvent-anion charge transfer in oxidative degradation of battery electrolytes
Electrochemical stability windows of electrolytes largely determine the limitations of
operating regimes of lithium-ion batteries, but the degradation mechanisms are difficult to …
operating regimes of lithium-ion batteries, but the degradation mechanisms are difficult to …
Oxidative stabilization of dilute ether electrolytes via anion modification
State-of-the-art lithium metal batteries typically rely on ether electrolytes with high salt
concentration and/or fluorinated solvents to enable stable cycling. Their high manufacturing …
concentration and/or fluorinated solvents to enable stable cycling. Their high manufacturing …
Density functional theory study on structure information and modification design of solid polymer electrolytes containing ester-thioether groups
Z Wang, J Ren, Y Zhao, Y Lin, R Lang… - Journal of Solid State …, 2024 - Springer
Abstract Poly (ethylene glycol dimethacrylate-1, 2-ethanedithiol)(P (EDGMA-EDT)) and poly
(ethylene glycol dimethacrylate-3, 6-dioxy-1, 8-octanedithiol)(P (EDGMA-DODT)) are …
(ethylene glycol dimethacrylate-3, 6-dioxy-1, 8-octanedithiol)(P (EDGMA-DODT)) are …
Deciphering reduction stability of sulfone and fluorinated sulfone electrolytes: Insight from quantum chemical calculations
F Du, T Ye, Y Shi, Y Zhang, Z Qiu, W Liu, T Lv, S Duan… - Chemical Physics, 2023 - Elsevier
Sulfones and fluorinated sulfones are preferred in high-voltage lithium-ion batteries, but the
reasons for their decreased stability in various lithium salt electrolytes remain unknown …
reasons for their decreased stability in various lithium salt electrolytes remain unknown …
Cathode electrolyte interface of lithium difluorobis (oxalato) phosphate at 4.4 V operation of LiCoO2 for high-energy lithium-ion batteries
For the electrolyte of lithium-ion batteries (LIBs), lithium difluorobis (oxalato) phosphate (Li-
PF 2 C 4 O 8) salt supports high surface stability of the positive electrode of LiCoO 2, even …
PF 2 C 4 O 8) salt supports high surface stability of the positive electrode of LiCoO 2, even …
Ni-stabilizing additives for completion of Ni-rich layered cathode systems in lithium-ion batteries: An Ab initio study
We propose the development of Ni-stabilizing electrolyte additives to fundamentally prevent
the degradation of Ni-rich layered cathode systems in lithium-ion batteries because unstable …
the degradation of Ni-rich layered cathode systems in lithium-ion batteries because unstable …
Ab initio study of the operating mechanisms of tris (trimethylsilyl) phosphite as a multifunctional additive for Li-ion batteries
Abstract Tris (trimethylsilyl) phosphite (P (OSi (CH 3) 3) 3) is a multifunctional electrolyte
additive for scavenging HF and forming a cathode electrolyte interphase (CEI). Systematic …
additive for scavenging HF and forming a cathode electrolyte interphase (CEI). Systematic …