Conductive Metal‐Organic Frameworks: Electronic Structure and Electrochemical Applications

A Nath, KS Asha, S Mandal - Chemistry–A European Journal, 2021 - Wiley Online Library
Smarter and minimization of devices are consistently substantial to shape the energy
landscape. Significant amounts of endeavours have come forward as promising steps to …

Iron (II) mediated supramolecular architectures with schiff bases and their spin-crossover properties

D Tesfaye, W Linert, M Gebrezgiabher, Y Bayeh… - Molecules, 2023 - mdpi.com
Supramolecular architectures, which are formed through the combination of inorganic metal
cations and organic ligands by self-assembly, are one of the techniques in modern chemical …

Solution Spin Crossover Versus Speciation Effects: A Cautionary Tale

S Sundaresan, S Brooker - Inorganic Chemistry, 2023 - ACS Publications
Two acyclic tetradentate Schiff base ligands, HLX–OH (X= H and Br), were synthesised by 2:
1 condensation of either 2-pyridinecarboxaldehyde or 5-bromo-2-pyridinecarboxaldehyde …

Synergetic Spin-Crossover and Luminescent Properties in a Multifunctional 2D Iron (II) Coordination Polymer

J Wang, M Kong, XJ Song, Y **g, Y Zhao… - Inorganic …, 2022 - ACS Publications
We designed and synthesized a strong fluorescent tetradentate pyridine ligand, 3, 6, 11, 12-
tetra (pyridin-4-yl) dibenzo [a, c] phenazine (TPDP), by covalently grafting pyridyl to …

A Family of Heterobimetallic Cubes Shows Spin‐Crossover Behaviour Near Room Temperature

M Hardy, J Tessarolo, JJ Holstein… - Angewandte Chemie …, 2021 - Wiley Online Library
Abstract Using 4‐(4′‐pyridyl) aniline as a simple organic building block in combination with
three different aldehyde components together with metal (II) salts gave three different Fe8Pt6 …

A Smart Molecule Showing Spin Crossover Responsive Aggregation-Induced Emission

C Yi, YS Meng, L Zhao, NT Yao, Q Liu, W Wen… - CCS …, 2023 - chinesechemsoc.org
The utilization of spin crossover (SCO) to modulate the luminescence properties in smart
multifunctional materials and multichannel sensors is promising. However, it is challenging …

Correlations between ligand field Δ o, spin crossover T 1/2 and redox potential E pa in a family of five dinuclear helicates

S Singh, S Brooker - Chemical Science, 2021 - pubs.rsc.org
A family of five new bis-bidentate azole–triazole Rat ligands (1, 3-bis (5-(azole)-4-isobutyl-
4H-1, 2, 4-triazol-3-yl) benzene), varying in choice of azole (2-imidazole, 4-imidazole, 1 …

Probing the generality of spin crossover complex T ½ vs. ligand 15 N NMR chemical shift correlations: towards predictable tuning

L Bondì, S Rodríguez-Jiménez, HLC Feltham… - Inorganic Chemistry …, 2021 - pubs.rsc.org
Four new bidentate 5-(Z-pyridine)-4-(4-methyl-phenyl)-3-phenyl-1, 2, 4-triazole ligands
LpytZ (meta-Z= CF3, Br, F, Me) and the corresponding family of [FeII (LpytZ) 2 (NCBH3) 2] …

Tuning spin-crossover transition temperatures in non-symmetrical homoleptic meridional/facial [Fe (didentate) 3] 2+ complexes: what for and who cares about it?

N Deorukhkar, C Besnard, L Guénée, C Piguet - Dalton Transactions, 2021 - pubs.rsc.org
The [FeN6] chromophores found in [Fe (didentate) 3] 2+ complexes, where didentate is a
non-symmetrical 2-(6-membered-heterocyclic ring)-benzimidazole ligand (Lk), exist as …

Construction of SCO-active Fe (II) mononuclear complexes from the thio-pybox ligand

Y Pan, YS Meng, Q Liu, WQ Gao, CH Liu, T Liu… - Inorganic …, 2020 - ACS Publications
The development of new spin-crossover complexes provides novel promising switching
materials with significant potential at the molecular level. Ter-imine-type molecules …