Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …

N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …

Syntheses, properties, and reactivity of N‐heterocyclic carbene–phosphinidene adducts are
reviewed. These adducts, formally built by combining a phosphinidene with a carbene, are …

N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two
different synthetic routes, either by reaction of As (SiMe3) 3 with 2, 2-difluoroimidazolines …

Half-sandwich complexes of the N-heterocyclic carbene-phosphinidene adduct [(IPr) PH](1,
IPr= 1, 3-bis (2, 6-diisopropylphenyl) imidazolin-2-ylidene) were prepared by its reaction …

The reactions of the N-heterocyclic carbene-phosphinidene adducts (NHC) PSiMe3 and
(NHC) PH with the dinuclear ruthenium and osmium complexes [(η6-p-cymene) MCl2] 2 (M …

The parent phosphinidene SIMesPH (1)(SIMes= 1, 3-bis (2, 4, 6-trimethylphenyl) imidazolin-
2-ylidene) was treated with benzyl potassium to form the metalated species SIMesPK (2) …

In this contribution we describe the general use of aryl-substituted triphosphiranes (Ar3P3;
Ar= Mes, Dip, Tip) as phosphinidene transfer reagents towards N-heterocyclic carbenes …

Herein, we present the synthesis and characterisation of new group 15 element compounds
with low valent phosphorus atoms as substituents. This new series of compounds includes …

Four‐membered rings with a P2BCh core (Ch= S, Se) have been synthesized by the
reaction of phosphinidene chalcogenide (Ar* P= Ch) and phosphaborene (Mes* P= BNR2) …