Solvent effects in palladium catalysed cross-coupling reactions

J Sherwood, JH Clark, IJS Fairlamb, JM Slattery - Green Chemistry, 2019 - pubs.rsc.org
Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …

Value-added processing of crude glycerol into chemicals and polymers

X Luo, X Ge, S Cui, Y Li - Bioresource Technology, 2016 - Elsevier
Crude glycerol is a low-value byproduct which is primarily obtained from the biodiesel
production process. Its composition is significantly different from that of pure glycerol. Crude …

Electrochemical biomass upgrading coupled with hydrogen production under industrial‐level current density

Q Qian, X He, Z Li, Y Chen, Y Feng… - Advanced …, 2023 - Wiley Online Library
As promising hydrogen energy carrier, formic acid (HCOOH) plays an indispensable role in
building a complete industry chain of a hydrogen economy. Currently, the biomass …

Co-electrolysis of CO2 and glycerol as a pathway to carbon chemicals with improved technoeconomics due to low electricity consumption

S Verma, S Lu, PJA Kenis - Nature Energy, 2019 - nature.com
The renewable electricity-driven electroreduction of carbon dioxide (CO2) offers an
alternative pathway to producing carbon chemicals that are traditionally manufactured using …

Recent advances in thermo-, photo-, and electrocatalytic glycerol oxidation

G Dodekatos, S Schünemann, H Tüysüz - ACS Catalysis, 2018 - ACS Publications
Glycerol is a highly versatile molecule because of its three hydroxyl groups and can be
transformed to a plethora of different value-added fine chemicals and products. It is an …

Constructing multifunctional 'Nanoplatelet-on-Nanoarray'electrocatalyst with unprecedented activity towards novel selective organic oxidation reactions to boost …

X Deng, M Li, Y Fan, L Wang, XZ Fu, JL Luo - Applied Catalysis B …, 2020 - Elsevier
Replacing oxygen evolution reaction with thermodynamically more favorable organic
oxidation reactions is considered as attractive approach to enhance the energy conversion …

Critical assessment of the sustainability of deep eutectic solvents: a case study on six choline chloride-based mixtures

S Nejrotti, A Antenucci, C Pontremoli, L Gontrani… - ACS …, 2022 - ACS Publications
An outline of the advantages, in terms of sustainability, of Deep Eutectic Solvents (DESs) is
provided, by analyzing some of the most popular DESs, obtained by the combination of …

Operando mechanistic studies of selective oxidation of glycerol to dihydroxyacetone over amorphous cobalt oxide

TG Vo, PY Ho, CY Chiang - Applied Catalysis B: Environmental, 2022 - Elsevier
In this work, cobalt oxide (CoO x) has been demonstrated as an efficient and selective
electrocatalyst for producing value-added dihydroxyacetone (DHA) from industrial by …

How to change the reaction chemistry on nonprecious metal oxide nanostructure materials for electrocatalytic oxidation of biomass‐derived glycerol to renewable …

LS Oh, M Park, YS Park, Y Kim, W Yoon… - Advanced …, 2023 - Wiley Online Library
Au and Pt are well‐known catalysts for electrocatalytic oxidation of biomass‐derived
glycerol. Although some nonprecious‐metal‐based materials to replace the costly Au and Pt …

WO3-based materials for photoelectrocatalytic glycerol upgrading into glyceraldehyde: Unravelling the synergistic photo-and electro-catalytic effects

J Yu, J Gonzalez-Cobos, F Dappozze… - Applied Catalysis B …, 2022 - Elsevier
The photoelectrocatalytic (PEC) glycerol oxidation has emerged as a promising technology
for the simultaneous valorization of this biomass waste and hydrogen production. Herein, we …