Solvent effects in palladium catalysed cross-coupling reactions

J Sherwood, JH Clark, IJS Fairlamb, JM Slattery - Green Chemistry, 2019‏ - pubs.rsc.org
Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …

Frontiers in photoelectrochemical catalysis: a focus on valuable product synthesis

MG Sendeku, TA Shifa, FT Dajan… - Advanced …, 2024‏ - Wiley Online Library
Photoelectrochemical (PEC) catalysis provides the most promising avenue for producing
value‐added chemicals and consumables from renewable precursors. Over the last …

Electrochemical biomass upgrading coupled with hydrogen production under industrial‐level current density

Q Qian, X He, Z Li, Y Chen, Y Feng… - Advanced …, 2023‏ - Wiley Online Library
As promising hydrogen energy carrier, formic acid (HCOOH) plays an indispensable role in
building a complete industry chain of a hydrogen economy. Currently, the biomass …

Co-electrolysis of CO2 and glycerol as a pathway to carbon chemicals with improved technoeconomics due to low electricity consumption

S Verma, S Lu, PJA Kenis - Nature Energy, 2019‏ - nature.com
The renewable electricity-driven electroreduction of carbon dioxide (CO2) offers an
alternative pathway to producing carbon chemicals that are traditionally manufactured using …

Recent advances in thermo-, photo-, and electrocatalytic glycerol oxidation

G Dodekatos, S Schünemann, H Tüysüz - ACS Catalysis, 2018‏ - ACS Publications
Glycerol is a highly versatile molecule because of its three hydroxyl groups and can be
transformed to a plethora of different value-added fine chemicals and products. It is an …

How to change the reaction chemistry on nonprecious metal oxide nanostructure materials for electrocatalytic oxidation of biomass‐derived glycerol to renewable …

LS Oh, M Park, YS Park, Y Kim, W Yoon… - Advanced …, 2023‏ - Wiley Online Library
Au and Pt are well‐known catalysts for electrocatalytic oxidation of biomass‐derived
glycerol. Although some nonprecious‐metal‐based materials to replace the costly Au and Pt …

Critical assessment of the sustainability of deep eutectic solvents: a case study on six choline chloride-based mixtures

S Nejrotti, A Antenucci, C Pontremoli, L Gontrani… - ACS …, 2022‏ - ACS Publications
An outline of the advantages, in terms of sustainability, of Deep Eutectic Solvents (DESs) is
provided, by analyzing some of the most popular DESs, obtained by the combination of …

From waste to value–Glycerol electrooxidation for energy conversion and chemical production

M Braun, CS Santana, AC Garcia… - Current opinion in green …, 2023‏ - Elsevier
Defossilation of chemical industry, aiming at reducing CO 2 emissions, is constrained by the
fact that many chemical products used today are carbon-based. To overcome this vicious …

Value-added processing of crude glycerol into chemicals and polymers

X Luo, X Ge, S Cui, Y Li - Bioresource technology, 2016‏ - Elsevier
Crude glycerol is a low-value byproduct which is primarily obtained from the biodiesel
production process. Its composition is significantly different from that of pure glycerol. Crude …

Current and future trends for crude glycerol upgrading to high value-added products

MH Moklis, S Cheng, JS Cross - Sustainability, 2023‏ - mdpi.com
Crude glycerol is the main byproduct of biodiesel manufacturing from oleaginous crops and
other biomass-derived oils. Approximately 10% crude glycerol is produced with every batch …