Metalated covalent organic frameworks: from synthetic strategies to diverse applications

Q Guan, LL Zhou, YB Dong - Chemical Society Reviews, 2022 - pubs.rsc.org
Covalent organic frameworks (COFs) are a class of organic crystalline porous materials
discovered in the early 21st century that have become an attractive class of emerging …

Confining enzymes in porous organic frameworks: from synthetic strategy and characterization to healthcare applications

S Huang, G Chen, G Ouyang - Chemical Society Reviews, 2022 - pubs.rsc.org
Enzymes are a class of natural catalysts with high efficiency, specificity, and selectivity
unmatched by their synthetic counterparts and dictate a myriad of reactions that constitute …

Photocatalytic sacrificial H2 evolution dominated by micropore-confined exciton transfer in hydrogen-bonded organic frameworks

Q Zhou, Y Guo, Y Zhu - Nature Catalysis, 2023 - nature.com
Organic semiconductors are attractive photocatalysts, but their quantum yields are limited by
the transfer of photogenerated charges to the surface. A promising strategy for low-loss …

Accelerated synthesis and discovery of covalent organic framework photocatalysts for hydrogen peroxide production

W Zhao, P Yan, B Li, M Bahri, L Liu… - Journal of the …, 2022 - ACS Publications
A high-throughput sonochemical synthesis and testing strategy was developed to discover
covalent organic frameworks (COFs) for photocatalysis. In total, 76 conjugated polymers …

Recent advances in the use of covalent organic frameworks as heterogenous photocatalysts in organic synthesis

A López‐Magano, S Daliran, AR Oveisi… - Advanced …, 2023 - Wiley Online Library
Organic photochemistry is intensely developed in the 1980s, in which the nature of excited
electronic states and the energy and electron transfer processes are thoroughly studied and …

Nanoscale covalent organic frameworks for enhanced photocatalytic hydrogen production

W Zhao, L Luo, M Cong, X Liu, Z Zhang, M Bahri… - Nature …, 2024 - nature.com
Nanosizing confers unique functions in materials such as graphene and quantum dots.
Here, we present two nanoscale-covalent organic frameworks (nano-COFs) that exhibit …

Covalent organic frameworks for CO 2 capture: from laboratory curiosity to industry implementation

H Li, A Dilipkumar, S Abubakar, D Zhao - Chemical Society Reviews, 2023 - pubs.rsc.org
CO2 concentration in the atmosphere has increased by about 40% since the 1960s. Among
various technologies available for carbon capture, adsorption and membrane processes …

Donor-acceptor-based conjugated polymers for photocatalytic energy conversion

C Yang, B Cheng, J Xu, J Yu, S Cao - EnergyChem, 2024 - Elsevier
Photocatalytic solar-to-chemical energy conversion is deemed to be a promising, eco-
friendly, and low-energy input strategy for addressing the energy crisis. Donor− acceptor (D …

Fluorination of covalent organic framework reinforcing the confinement of Pd nanoclusters enhances hydrogen peroxide photosynthesis

Y Liu, L Li, H Tan, N Ye, Y Gu, S Zhao… - Journal of the …, 2023 - ACS Publications
Metal-isolated clusters (MICs) physically confined on photoactive materials are of great
interest in the field of photosynthesis of hydrogen peroxide (H2O2). Despite recent important …

Growth of single-crystal imine-linked covalent organic frameworks using amphiphilic amino-acid derivatives in water

Z Zhou, L Zhang, Y Yang, IJ Vitorica-Yrezabal… - Nature Chemistry, 2023 - nature.com
A core feature of covalent organic frameworks (COFs) is crystallinity, but current
crystallization processes rely substantially on trial and error, chemical intuition and large …