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Methane oxidation to methanol
The direct transformation of methane to methanol remains a significant challenge for
operation at a larger scale. Central to this challenge is the low reactivity of methane at …
operation at a larger scale. Central to this challenge is the low reactivity of methane at …
Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
In Situ UV–Vis–NIR Absorption Spectroscopy and Catalysis
This review highlights in situ UV–vis–NIR range absorption spectroscopy in catalysis. A
variety of experimental techniques identifying reaction mechanisms, kinetics, and structural …
variety of experimental techniques identifying reaction mechanisms, kinetics, and structural …
Small-pore zeolites: synthesis and catalysis
In the past decade or so, small-pore zeolites have received greater attention than large-and
medium-pore molecular sieves that have historically dominated the literature. This is …
medium-pore molecular sieves that have historically dominated the literature. This is …
Dynamic multinuclear sites formed by mobilized copper ions in NOx selective catalytic reduction
Copper ions exchanged into zeolites are active for the selective catalytic reduction (SCR) of
nitrogen oxides (NO x) with ammonia (NH3), but the low-temperature rate dependence on …
nitrogen oxides (NO x) with ammonia (NH3), but the low-temperature rate dependence on …
Activation and conversion of alkanes in the confined space of zeolite-type materials
Microporous zeolite-type materials, with crystalline porous structures formed by well-defined
channels and cages of molecular dimensions, have been widely employed as …
channels and cages of molecular dimensions, have been widely employed as …
Bioinspired metal–organic framework catalysts for selective methane oxidation to methanol
Particulate methane monooxygenase (pMMO) is an enzyme that oxidizes methane to
methanol with high activity and selectivity. Limited success has been achieved in …
methanol with high activity and selectivity. Limited success has been achieved in …
Copper–oxygen complexes revisited: structures, spectroscopy, and reactivity
CE Elwell, NL Gagnon, BD Neisen, D Dhar… - Chemical …, 2017 - ACS Publications
A longstanding research goal has been to understand the nature and role of copper–oxygen
intermediates within copper-containing enzymes and abiological catalysts. Synthetic …
intermediates within copper-containing enzymes and abiological catalysts. Synthetic …
Active sites and mechanisms in the direct conversion of methane to methanol using Cu in zeolitic hosts: a critical examination
In this critical review we examine the current state of our knowledge in respect of the nature
of the active sites in copper containing zeolites for the selective conversion of methane to …
of the active sites in copper containing zeolites for the selective conversion of methane to …
Catalysis in a cage: condition-dependent speciation and dynamics of exchanged Cu cations in SSZ-13 zeolites
The relationships among the macroscopic compositional parameters of a Cu-exchanged
SSZ-13 zeolite catalyst, the types and numbers of Cu active sites, and activity for the …
SSZ-13 zeolite catalyst, the types and numbers of Cu active sites, and activity for the …