Giant Crown-Shaped Dy34 Nanocluster with High Acid–Base Stability Assembled by an out-to-in Growth Mechanism

YL Li, HL Wang, ZH Zhu, FP Liang, HH Zou - Inorganic Chemistry, 2022 - ACS Publications
Lanthanoid metal ions have large ionic radii, complex coordination modes, and easy
distortion of coordination spheres, but the design and synthesis of high-nucleation …

Mixed-sandwich titanium (III) qubits on Au (111): electron delocalization ruled by molecular packing

M Briganti, G Serrano, L Poggini, AL Sorrentino… - Nano Letters, 2022 - ACS Publications
Organometallic sandwich complexes are versatile molecular systems that have been
recently employed for single-molecule manipulation and spin sensing experiments. Among …

Structural manipulation of spin excitations in a molecular junction

M Kögler, N Néel, L Limot, J Kröger - Nano Letters, 2024 - ACS Publications
Single metallocene molecules act as sensitive spin detectors when decorating the probe of
a scanning tunneling microscope (STM). However, the impact of the atomic-scale electrode …

Structure, assembly mechanism and magnetic properties of heterometallic dodecanuclear nanoclusters Dy III4 M II8 (M= Ni, Co)

S Yu, QH Zhang, Z Chen, HH Zou, H Hu… - Inorganic Chemistry …, 2021 - pubs.rsc.org
The formation of heterometallic clusters usually involves a much more complex self-
assembly process than that of homometallic clusters. Thus the tracking of their assembly …

Tilted Spins in Chains of Molecular Switches on Pb (100)

M Treichel, J Möller, X Meng, F Gutzeit, R Herges… - ACS …, 2024 - ACS Publications
A complex based on a Ni (II) porphyrin exhibiting spin crossover on Ag (111) is studied on
Pb (100) by scanning tunneling microscopy at 0.3 K. Strong molecular interactions between …

Strong Electron-Vibration Signals in Weakly Coupled Molecular Junctions: Activation of Spin-Crossover

Y Zhang, S Giménez-Santamarina… - Nano Letters, 2024 - ACS Publications
Manipulating individual molecular spin states with electronic current has the potential to
revolutionize quantum information devices. However, it is still unclear how a current can …

From Solution to Surface: Persistence of the Diradical Character of a Diindenoanthracene Derivative on a Metallic Substrate

J Hieulle, C Garcia Fernandez, N Friedrich… - The Journal of …, 2023 - ACS Publications
Organic diradicals are envisioned as elementary building blocks for designing a new
generation of spintronic devices and have been used in constructing prototypical field effect …

Superconducting scanning tunneling microscope tip to reveal sub-millielectronvolt magnetic energy variations on surfaces

C Mier, B Verlhac, L Garnier, R Robles… - The Journal of …, 2021 - ACS Publications
Combining the complex ordering ability of molecules with their local magnetic properties is a
little-explored technique to tailor spin structures on surfaces. However, revealing the …

Spin-Flip Inelastic Electron Tunneling Spectroscopy on a CuCu4 Metallacrown Complex on Au (111)

R Ranecki, S Lach, A Lüpke… - The Journal of …, 2023 - ACS Publications
Spin-flip inelastic tunneling spectroscopy (SF-IETS) is an outstanding technique to
investigate elementary spin excitation of adsorbed atoms, molecules, and their assemblies …

Mechanism and Application of Magnetic Anisotropy of a Single-Molecule Magnet Modulated by a Molecular Junction

X Liu, D Legut, Q Zhang - The Journal of Physical Chemistry C, 2022 - ACS Publications
The development of spintronic and quantum computing has inspired researchers to search
for single-molecule magnets with stable structures that could be modulated repetitively …