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Mass transfer kinetics, band broadening and column efficiency
F Gritti, G Guiochon - Journal of Chromatography A, 2012 - Elsevier
Important progress was recently made in our understanding of the physico-chemical aspects
of mass transfer kinetics in chromatographic columns, in methods used for accurate …
of mass transfer kinetics in chromatographic columns, in methods used for accurate …
Recent advancements and future directions of superficially porous chiral stationary phases for ultrafast high-performance enantioseparations
This review focuses on the use of superficially porous particles (SPPs) as chiral stationary
phases for ultra-high performance liquid enantioseparations. In contrast to what happened …
phases for ultra-high performance liquid enantioseparations. In contrast to what happened …
Enhancing separation abilities of “low-performance” metal–organic framework stationary phases through size control
SS Meng, T Han, YH Gu, C Zeng, WQ Tang… - Analytical …, 2022 - ACS Publications
Peak broadening and peak tailing are common but rebarbative phenomena that always
occur when using metal–organic frameworks (MOFs) as stationary phases. These …
occur when using metal–organic frameworks (MOFs) as stationary phases. These …
Effect of temperature and flow-rate on analysis of basic compounds in high-performance liquid chromatography using a reversed-phase column
DV McCalley - Journal of Chromatography A, 2000 - Elsevier
The peak shape and retention of some basic probes together with a neutral reference
compound were investigated as a function of temperature and flow-rate using a reversed …
compound were investigated as a function of temperature and flow-rate using a reversed …
[HTML][HTML] The correctness of van't Hoff plots in chiral and achiral chromatography
A Sepsey, É Horváth, M Catani, A Felinger - Journal of Chromatography A, 2020 - Elsevier
Abstract van't Hoff plots (logarithm of the retention factor, ln k, vs. the reciprocal of absolute
temperature, 1/T) are commonly used in chromatographic studies to characterize the …
temperature, 1/T) are commonly used in chromatographic studies to characterize the …
Study of mechanisms of chiral discrimination of amino acids and their derivatives on a teicoplanin-based chiral stationary phase
A Cavazzini, G Nadalini, F Dondi, F Gasparrini… - … of Chromatography A, 2004 - Elsevier
The behavior of a series of amino acids and some of their methyl ester hydrochloride, N-
acetyl and N-tert-butyloxycarbonyl derivatives has been investigated on a teicoplanin-based …
acetyl and N-tert-butyloxycarbonyl derivatives has been investigated on a teicoplanin-based …
Analysis of peak asymmetry in chromatography
Z Pápai, TL Pap - Journal of Chromatography A, 2002 - Elsevier
The knowledge of the symmetry of chromatographic peaks is extremely important regarding
the digital signal processing. The significant deviation of the peak shape from the …
the digital signal processing. The significant deviation of the peak shape from the …
[HTML][HTML] Correctness of the Van't Hoff analysis for homogeneous or heterogeneous retention
D Szerencsés, A Sepsey, A Felinger - Journal of Chromatography A, 2023 - Elsevier
It is already known that the physical meaning of the numerical values of the calculated
enthalpy (ΔH) and entropy (ΔS) change in chromatography via the van't Hoff plot analysis is …
enthalpy (ΔH) and entropy (ΔS) change in chromatography via the van't Hoff plot analysis is …
Shedding light on mechanisms leading to convex-upward van Deemter curves on a cellulose tris (4-chloro-3-methylphenylcarbamate)-based chiral stationary phase
S Felletti, C De Luca, G Lievore, T Chenet… - … of Chromatography A, 2020 - Elsevier
An unusual convex-upward van Deemter curve was observed for the more retained
enantiomer of a chiral sulfoxide (2-(benzylsulfinyl) benzamide) on a cellulose tris (4-chloro-3 …
enantiomer of a chiral sulfoxide (2-(benzylsulfinyl) benzamide) on a cellulose tris (4-chloro-3 …
Molecular dynamic theories in chromatography
A Felinger - Journal of Chromatography A, 2008 - Elsevier
The molecular dynamic model of chromatography is a microscopic model that consists of
two fundamental processes:(i) the random migration of the molecules in the mobile phase …
two fundamental processes:(i) the random migration of the molecules in the mobile phase …