Impact of the valence band energy alignment at the hole-collecting interface on the photostability of wide band-gap perovskite solar cells

LVT Merino, CE Petoukhoff, O Matiash, AS Subbiah… - Joule, 2024 - cell.com
This work discusses the need to enhance charge carrier collection to minimize halide
segregation in wide band-gap (WBG) perovskites. Here, we systematically elucidate the …

Temperature‐dependent reversal of phase segregation in mixed‐halide perovskites

AD Wright, JB Patel, MB Johnston… - Advanced …, 2023 - Wiley Online Library
Understanding the mechanism of light‐induced halide segregation in mixed‐halide
perovskites is essential for their application in multijunction solar cells. Here …

How Photogenerated I2 Induces I‐Rich Phase Formation in Lead Mixed Halide Perovskites

Y Zhou, SCW van Laar, D Meggiolaro… - Advanced …, 2024 - Wiley Online Library
Bandgap tunability of lead mixed halide perovskites (LMHPs) is a crucial characteristic for
versatile optoelectronic applications. Nevertheless, LMHPs show the formation of iodide …

The promise of metal-halide-perovskite solar photovoltaics: A brief review

NP Padture - MRS Bulletin, 2023 - Springer
Solar photovoltaics (PVs) based on metal-halide perovskites (MHPs) have taken the
renewable-energy world by storm. The excitement stems from the promise of a high …

Phase segregation and sequential expulsion of iodide and bromide in photoirradiated Ruddlesden–Popper 2D perovskite films

PS Mathew, G Szabó, M Kuno, PV Kamat - ACS Energy Letters, 2022 - ACS Publications
Two-dimensional (2D) Ruddlesden–Popper mixed-halide perovskite films, BA2PbBr2I2,
undergo phase segregation when excited with visible light to generate bromide-and iodide …

Modeling the Photoelectrochemical Evolution of Lead-Based, Mixed-Halide Perovskites Due to Photosegregation

A Ruth, M Kuno - ACS nano, 2023 - ACS Publications
Lead-based, mixed-halide perovskites such as methylammonium lead iodide-bromide
[MAPb (I1–x Br x) 3] undergo anion photosegregation under illumination. This is observed …

Physics-driven discovery and bandgap engineering of hybrid perovskites

SL Sanchez, E Foadian, M Ziatdinov, J Yang… - Digital …, 2024 - pubs.rsc.org
The unique aspect of hybrid perovskites is their tunability, allowing the engineering of the
bandgap via substitution. From the application viewpoint, this allows creation of tandem cells …

Excitation Intensity- and Size-Dependent Halide Photosegregation in CsPb(I0.5Br0.5)3 Perovskite Nanocrystals

I Gushchina, V Trepalin, E Zaitsev, A Ruth, M Kuno - ACS nano, 2022 - ACS Publications
Although broad consensus exists that photoirradiation of mixed-halide lead perovskites
leads to anion segregation, no model today fully rationalizes all aspects of this near …

Defects in lead halide perovskite light-emitting diodes under electric field: from behavior to passivation strategies

N Jiang, G Ma, D Song, B Qiao, Z Liang, Z Xu… - Nanoscale, 2024 - pubs.rsc.org
Lead halide perovskites (LHPs) are emerging semiconductor materials for light-emitting
diodes (LEDs) owing to their unique structure and superior optoelectronic properties …

Thermodynamic band gap model for photoinduced phase segregation in mixed-halide perovskites

A Ruth, H Okrepka, P Kamat… - The Journal of Physical …, 2023 - ACS Publications
Provided is a comprehensive description of a band gap thermodynamic model, which
predicts and explains key features of photosegregation in lead-based, mixed-halide …