Metal–organic network-forming glasses

N Ma, S Horike - Chemical Reviews, 2022 - ACS Publications
The crystal–liquid–glass phase transition of coordination polymers (CPs) and metal–organic
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …

Metal–organic frameworks (MOFs) beyond crystallinity: amorphous MOFs, MOF liquids and MOF glasses

J Fonseca, T Gong, L Jiao, HL Jiang - Journal of Materials Chemistry A, 2021 - pubs.rsc.org
The field of metal–organic frameworks (MOFs) has been incorrectly believed to be purely
crystalline. However, non-crystalline MOFs (amorphous MOFs, MOF liquids, and MOF …

ZIF-62 glass foam self-supported membranes to address CH4/N2 separations

Z Yang, Y Belmabkhout, LN McHugh, D Ao, Y Sun… - Nature Materials, 2023 - nature.com
Membranes with ultrahigh permeance and practical selectivity could greatly decrease the
cost of difficult industrial gas separations, such as CH4/N2 separation. Advanced …

Liquid-phase sintering of lead halide perovskites and metal-organic framework glasses

J Hou, P Chen, A Shukla, A Krajnc, T Wang, X Li… - Science, 2021 - science.org
Lead halide perovskite (LHP) semiconductors show exceptional optoelectronic properties.
Barriers for their applications, however, lie in their polymorphism, instability to polar solvents …

Metal-organic framework functionalization and design strategies for advanced electrochemical energy storage devices

AE Baumann, DA Burns, B Liu, VS Thoi - Communications Chemistry, 2019 - nature.com
Metal-organic frameworks (MOFs) are a class of porous materials with unprecedented
chemical and structural tunability. Their synthetic versatility, long-range order, and rich host …

A MOF glass membrane for gas separation

Y Wang, H **, Q Ma, K Mo, H Mao… - Angewandte …, 2020 - Wiley Online Library
Metal–organic framework (MOF) glasses are promising candidates for membrane fabrication
due to their significant porosity, the ease of processing, and most notably, the potential to …

Conductive MOFs

WH Li, WH Deng, GE Wang, G Xu - EnergyChem, 2020 - Elsevier
Abstract Metal-organic frameworks (MOFs)/porous coordination polymers (PCPs) have
emerged as a new family of conductive solid materials with outstanding performances in a …

Electronic structure modeling of metal–organic frameworks

JL Mancuso, AM Mroz, KN Le, CH Hendon - Chemical reviews, 2020 - ACS Publications
Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …

Understanding glass through differential scanning calorimetry

Q Zheng, Y Zhang, M Montazerian, O Gulbiten… - Chemical …, 2019 - ACS Publications
Differential scanning calorimetry (DSC) is a powerful tool to address some of the most
challenging issues in glass science and technology, such as the nonequilibrium nature of …

Anisotropic reticular chemistry

W Xu, B Tu, Q Liu, Y Shu, CC Liang… - Nature Reviews …, 2020 - nature.com
Reticular chemistry has been focused on making simple structures in which a few kinds of
components are linked to make crystals such as metal–organic frameworks (MOFs). While …