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MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
A reticular chemistry guide for the design of periodic solids
Reticular chemistry—the linking of well-defined molecular building blocks by strong bonds
into crystalline extended frameworks—has enabled the synthesis of diverse metal–organic …
into crystalline extended frameworks—has enabled the synthesis of diverse metal–organic …
Recent progress in metal-organic frameworks as active materials for supercapacitors
Abstract Metal-organic frameworks (MOFs), also quoted as porous coordination polymers
(PCPs), are causing great concern in supercapacitors (SCs) field owing to their ultra-high …
(PCPs), are causing great concern in supercapacitors (SCs) field owing to their ultra-high …
Polymer networks: from plastics and gels to porous frameworks
Polymer networks, which are materials composed of many smaller components—referred to
as “junctions” and “strands”—connected together via covalent or non‐covalent …
as “junctions” and “strands”—connected together via covalent or non‐covalent …
Best practices for the synthesis, activation, and characterization of metal–organic frameworks
Metal–organic frameworks (MOFs) are structurally diverse materials comprised of inorganic
and organic components. As the rapidly expanding field of MOF research has demonstrated …
and organic components. As the rapidly expanding field of MOF research has demonstrated …
The chemistry and applications of metal-organic frameworks
Background Metal-organic frameworks (MOFs) are made by linking inorganic and organic
units by strong bonds (reticular synthesis). The flexibility with which the constituents' …
units by strong bonds (reticular synthesis). The flexibility with which the constituents' …
Single crystals of purely organic free-standing two-dimensional woven polymer networks
The aesthetic and practicality of macroscopic fabrics continue to encourage chemists to
weave molecules into interlaced patterns with the aim of providing emergent physical and …
weave molecules into interlaced patterns with the aim of providing emergent physical and …
Efficient and Selective Uptake of TcO4– by a Cationic Metal–Organic Framework Material with Open Ag+ Sites
99Tc is one of the most problematic radioisotopes in used nuclear fuel owing to its combined
features of high fission yield, long half-life, and high environmental mobility. There are only a …
features of high fission yield, long half-life, and high environmental mobility. There are only a …
Metal-Organic Frameworks: A promising solution for efficient removal of heavy metal ions and organic pollutants from industrial wastewater
The discharge of heavy metal ions and organic pollutants from industrial, agricultural, and
domestic activities poses a significant threat to water bodies and ecosystems. The …
domestic activities poses a significant threat to water bodies and ecosystems. The …
Extremely large 3D cages in metal–organic frameworks for nucleic acid extraction
Three-dimensional (3D) cages in the mesopore regime (2–50 nm) assembled from
molecular building blocks are highly desirable in biological applications; however, their …
molecular building blocks are highly desirable in biological applications; however, their …