Increased interest in chiral functional dyes has stimulated activity in the field of boron-
containing helicenes over the past few years. Despite the fact that the introduction of boron …

Expanded azahelicenes, as heteroanalogues of helically chiral helicenes, hold significant
potential for chiroptical materials. Nevertheless, their investigation and research have …

We report a neutral high-spin diradical of chiral C 2-symmetric bis [5] diazahelicene with Δ E
ST≈ 0.4 kcal mol–1, as determined by EPR spectroscopy/SQUID magnetometry. The …

A chiral shape‐persistent macrocyclic compound (Si‐[3]), designed by the C/Si substitution
in the spiro‐atom of spirobifluorene in the cyclic trimer (C‐[3]), has been successfully …

Development of chiral organic materials with a strong chiroptical response is crucial to
advance technologies based on circularly polarized luminescence, enantioselective …

The relationship between chemical structure and chiroptical properties is not always clearly
understood. Nowadays, efforts to develop new systems with enhanced optical properties …

The development of chiral compounds exhibiting circularly polarized luminescence (CPL)
has advanced remarkably in recent years. Designing CPL-active compounds requires an …

Establishing design principles to engineer molecules that exhibit strong circularly polarized
luminescence (CPL)‐brightness across the UV, visible and NIR spectral range remains an …

Helical fused anthracenes were elongated by fusing additional aromatic units at both ends
to yield novel expanded helicenes. Compounds [5] HA2N and [7] HA consisting of 19 and 21 …

Abstract A new chiral macrocycle 1-[6], consisting of six chiral spirobifluorene units linked in
a cyclic arrangement, was successfully synthesized via a homo-coupling of the …