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Relaxation in glassforming liquids and amorphous solids
The field of viscous liquid and glassy solid dynamics is reviewed by a process of posing the
key questions that need to be answered, and then providing the best answers available to …
key questions that need to be answered, and then providing the best answers available to …
Glass transition and phase state of organic compounds: dependency on molecular properties and implications for secondary organic aerosols in the atmosphere
Recently, it has been proposed that organic aerosol particles in the atmosphere can exist in
an amorphous semi-solid or solid (ie glassy) state. In this perspective, we analyse and …
an amorphous semi-solid or solid (ie glassy) state. In this perspective, we analyse and …
Fragility and thermodynamics in nonpolymeric glass-forming liquids
For nonpolymeric supercooled liquids, the empirical correlation m= 56 T g Δ C p (T g)∕ Δ H
m provides a reliable means of correlating dynamic and thermodynamic variables. The …
m provides a reliable means of correlating dynamic and thermodynamic variables. The …
New insights into the fragility dilemma in liquids
A compilation of data for small molecule organic, polymeric, and inorganic glass-forming
liquids shows that the original expectation, that there be a positive correlation between the …
liquids shows that the original expectation, that there be a positive correlation between the …
Temperature dependence of the electrical conductivity in EMIM-based ionic liquids: evidence of Vogel–Tamman–Fulcher behavior
J Vila, P Ginés, JM Pico, C Franjo, E Jiménez… - Fluid Phase …, 2006 - Elsevier
We present measurements of the electrical conductivity versus temperature for six pure 1-
ethyl-3-methyl imidazolium (EMIM) based ionic liquids (ILs) at atmospheric pressure. The …
ethyl-3-methyl imidazolium (EMIM) based ionic liquids (ILs) at atmospheric pressure. The …
Spatial correlations in the dynamics of glassforming liquids: Experimental determination of their temperature dependence
We use recently introduced three-point dynamic susceptibilities to obtain an experimental
determination of the temperature evolution of the number of molecules N corr that are …
determination of the temperature evolution of the number of molecules N corr that are …
Ionic liquids of chelated orthoborates as model ionic glassformers
Ionic liquids based on various chelated orthoborate anions of different N-containing onium
cations have been synthesized using an economic synthesis strategy. Most orthoborates do …
cations have been synthesized using an economic synthesis strategy. Most orthoborates do …
Glass forming ability in systems with competing orderings
Some liquids, if cooled rapidly enough to avoid crystallization, can be frozen into a
nonergodic glassy state. The tendency for a material to form a glass when quenched is …
nonergodic glassy state. The tendency for a material to form a glass when quenched is …
Impact of drug–polymer intermolecular interactions on dissolution performance of copovidone-based amorphous solid dispersions
For poorly soluble drugs formulated as amorphous solid dispersions (ASDs), fast and
complete release with the generation of drug-rich colloidal particles is beneficial for …
complete release with the generation of drug-rich colloidal particles is beneficial for …
Confinement of molecular liquids: Consequences on thermodynamic, static and dynamical properties of benzene and toluene
We relate the dynamical behavior of molecular liquids confined in mesoscopic cylindrical
pores to the thermodynamic properties, heat capacity and density and to the static structure …
pores to the thermodynamic properties, heat capacity and density and to the static structure …