Relaxation in glassforming liquids and amorphous solids

CA Angell, KL Ngai, GB McKenna… - Journal of applied …, 2000 - pubs.aip.org
The field of viscous liquid and glassy solid dynamics is reviewed by a process of posing the
key questions that need to be answered, and then providing the best answers available to …

Glass transition and phase state of organic compounds: dependency on molecular properties and implications for secondary organic aerosols in the atmosphere

T Koop, J Bookhold, M Shiraiwa… - Physical Chemistry …, 2011 - pubs.rsc.org
Recently, it has been proposed that organic aerosol particles in the atmosphere can exist in
an amorphous semi-solid or solid (ie glassy) state. In this perspective, we analyse and …

Fragility and thermodynamics in nonpolymeric glass-forming liquids

LM Wang, CA Angell, R Richert - The Journal of chemical physics, 2006 - pubs.aip.org
For nonpolymeric supercooled liquids, the empirical correlation m= 56 T g Δ C p (T g)∕ Δ H
m provides a reliable means of correlating dynamic and thermodynamic variables. The …

New insights into the fragility dilemma in liquids

D Huang, GB McKenna - The Journal of chemical physics, 2001 - pubs.aip.org
A compilation of data for small molecule organic, polymeric, and inorganic glass-forming
liquids shows that the original expectation, that there be a positive correlation between the …

Temperature dependence of the electrical conductivity in EMIM-based ionic liquids: evidence of Vogel–Tamman–Fulcher behavior

J Vila, P Ginés, JM Pico, C Franjo, E Jiménez… - Fluid Phase …, 2006 - Elsevier
We present measurements of the electrical conductivity versus temperature for six pure 1-
ethyl-3-methyl imidazolium (EMIM) based ionic liquids (ILs) at atmospheric pressure. The …

Spatial correlations in the dynamics of glassforming liquids: Experimental determination of their temperature dependence

C Dalle-Ferrier, C Thibierge, C Alba-Simionesco… - Physical Review E …, 2007 - APS
We use recently introduced three-point dynamic susceptibilities to obtain an experimental
determination of the temperature evolution of the number of molecules N corr that are …

Ionic liquids of chelated orthoborates as model ionic glassformers

W Xu, LM Wang, RA Nieman… - The Journal of Physical …, 2003 - ACS Publications
Ionic liquids based on various chelated orthoborate anions of different N-containing onium
cations have been synthesized using an economic synthesis strategy. Most orthoborates do …

Glass forming ability in systems with competing orderings

J Russo, F Romano, H Tanaka - Physical Review X, 2018 - APS
Some liquids, if cooled rapidly enough to avoid crystallization, can be frozen into a
nonergodic glassy state. The tendency for a material to form a glass when quenched is …

Confinement of molecular liquids: Consequences on thermodynamic, static and dynamical properties of benzene and toluene

C Alba-Simionesco, G Dosseh, E Dumont… - The European Physical …, 2003 - Springer
We relate the dynamical behavior of molecular liquids confined in mesoscopic cylindrical
pores to the thermodynamic properties, heat capacity and density and to the static structure …

Metal-organic framework MIL-100 (Fe) as the stationary phase for both normal-phase and reverse-phase high performance liquid chromatography

YY Fu, CX Yang, XP Yan - Journal of Chromatography A, 2013 - Elsevier
Metal-organic framework MIL-100 (Fe) was explored as a novel stationary phase for both
normal-phase and reverse-phase high performance liquid chromatography. Two groups of …