C–H bond functionalization by high-valent cobalt catalysis: current progress, challenges and future perspectives

L Lukasevics, A Cizikovs, L Grigorjeva - Chemical Communications, 2021 - pubs.rsc.org
Over the last decade, high-valent cobalt catalysis has earned a place in the spotlight as a
valuable tool for C–H activation and functionalization. Since the discovery of its unique …

[PDF][PDF] The green chemistry paradigm in modern organic synthesis

SG Zlotin, KS Egorova, VP Ananikov, AA Akulov… - Russ. Chem …, 2023 - researchgate.net
After the appearance of the green chemistry concept, which was introduced in the chemistry
vocabulary in the early 1990s, its main statements have been continuously developed and …

Tandem Reactions involving 1, 4‐Palladium Migrations

MY Li, D Wei, CG Feng, GQ Lin - Chemistry–An Asian Journal, 2022 - Wiley Online Library
Transition‐metal‐catalyzed tandem reactions have become a mainstay in organic chemistry
owing to their high atom‐and step‐economies. Metal‐migration‐based tandem reactions …

Synthesis of Indenone Derivatives by Rh (III)-Catalyzed C–H Functionalization of Sulfoxonium Ylides with 1, 3-Diynes

S Kumar, S Nunewar, TK Sabbi, V Kanchupalli - Organic Letters, 2022 - ACS Publications
The transition-metal-catalyzed C–H functionalization of sulfoxonium ylides with alkynes
formally participates in [4+ 2] annulations to deliver the naphthol scaffolds. In contrast, herein …

1, 3-diene-based AIEgens: Stereoselective synthesis and applications

XM Nong, A Gu, S Zhai, J Li, ZY Yue, MY Li, Y Liu - Iscience, 2024 - cell.com
In recent years, significant advancements have been made in the synthesis and application
of 1, 3-dienes. This specific structural motif has garnered significant attention from …

The Pyridotriazole Works as a Traceless Directing Group: AC–H Activation/Annulation Cascade Reaction with Iodonium Ylides

G Lv, Q Zhang, C Zhang, Y Chen, Z Lin, R Lai… - Organic …, 2023 - ACS Publications
A novel Rh-catalyzed cascade reaction of pyridotriazoles with iodonium ylides is reported.
This one-pot procedure involves a triazole-directed ortho-position C–H carbene insertion …

Recent advances in rhodium-catalyzed C (sp 2)–H (hetero) arylation

Z Yang, JT Yu, C Pan - Organic & Biomolecular Chemistry, 2021 - pubs.rsc.org
Arylation is a common behaviour in organic synthesis for the construction of complex
structures, especially the biaryls. Among those reported arylation procedures, transition …

Nitro–a traceless directing group for reversing the radical site-selectivity of styrene derivatives

Z Zhang, X Zhang, Y Wang, Y Liu, Y Wang… - Organic Chemistry …, 2023 - pubs.rsc.org
2-Quinolone is a privileged nitrogen heterocycle that is found in various bioactive and
functional substances. Herein, a two-component [4+ 2] annulation reaction of styrene …

Access to π-Extended Heterocycles Containing Pyrrolo-Coumarin Cores Involving− COCH3 as a Traceless Directing Group and Materializing Two Successive sp2C …

D Das, AR Das - The Journal of Organic Chemistry, 2022 - ACS Publications
An efficient protocol has been developed for the preparation of π-extended N-heterocycles
involving a Rh (III)-catalyzed C–H activation reaction starting from 3-acetamidocoumarins …

Rhodium-Catalyzed C2-Alkylation of Indoles with Cyclopropanols Using N,N-Dialkylcarbamoyl as a Traceless Directing Group

K Ramachandran, P Anbarasan - Organic Letters, 2022 - ACS Publications
An efficient rhodium-catalyzed synthesis of C2-alkylated NH-free indoles has been achieved
from substituted indoles and cyclopropanols. The reaction allows the synthesis of various C2 …