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C–H bond functionalization by high-valent cobalt catalysis: current progress, challenges and future perspectives
L Lukasevics, A Cizikovs, L Grigorjeva - Chemical Communications, 2021 - pubs.rsc.org
Over the last decade, high-valent cobalt catalysis has earned a place in the spotlight as a
valuable tool for C–H activation and functionalization. Since the discovery of its unique …
valuable tool for C–H activation and functionalization. Since the discovery of its unique …
[PDF][PDF] The green chemistry paradigm in modern organic synthesis
After the appearance of the green chemistry concept, which was introduced in the chemistry
vocabulary in the early 1990s, its main statements have been continuously developed and …
vocabulary in the early 1990s, its main statements have been continuously developed and …
Tandem Reactions involving 1, 4‐Palladium Migrations
MY Li, D Wei, CG Feng, GQ Lin - Chemistry–An Asian Journal, 2022 - Wiley Online Library
Transition‐metal‐catalyzed tandem reactions have become a mainstay in organic chemistry
owing to their high atom‐and step‐economies. Metal‐migration‐based tandem reactions …
owing to their high atom‐and step‐economies. Metal‐migration‐based tandem reactions …
Synthesis of Indenone Derivatives by Rh (III)-Catalyzed C–H Functionalization of Sulfoxonium Ylides with 1, 3-Diynes
The transition-metal-catalyzed C–H functionalization of sulfoxonium ylides with alkynes
formally participates in [4+ 2] annulations to deliver the naphthol scaffolds. In contrast, herein …
formally participates in [4+ 2] annulations to deliver the naphthol scaffolds. In contrast, herein …
1, 3-diene-based AIEgens: Stereoselective synthesis and applications
In recent years, significant advancements have been made in the synthesis and application
of 1, 3-dienes. This specific structural motif has garnered significant attention from …
of 1, 3-dienes. This specific structural motif has garnered significant attention from …
The Pyridotriazole Works as a Traceless Directing Group: AC–H Activation/Annulation Cascade Reaction with Iodonium Ylides
G Lv, Q Zhang, C Zhang, Y Chen, Z Lin, R Lai… - Organic …, 2023 - ACS Publications
A novel Rh-catalyzed cascade reaction of pyridotriazoles with iodonium ylides is reported.
This one-pot procedure involves a triazole-directed ortho-position C–H carbene insertion …
This one-pot procedure involves a triazole-directed ortho-position C–H carbene insertion …
Recent advances in rhodium-catalyzed C (sp 2)–H (hetero) arylation
Z Yang, JT Yu, C Pan - Organic & Biomolecular Chemistry, 2021 - pubs.rsc.org
Arylation is a common behaviour in organic synthesis for the construction of complex
structures, especially the biaryls. Among those reported arylation procedures, transition …
structures, especially the biaryls. Among those reported arylation procedures, transition …
Nitro–a traceless directing group for reversing the radical site-selectivity of styrene derivatives
Z Zhang, X Zhang, Y Wang, Y Liu, Y Wang… - Organic Chemistry …, 2023 - pubs.rsc.org
2-Quinolone is a privileged nitrogen heterocycle that is found in various bioactive and
functional substances. Herein, a two-component [4+ 2] annulation reaction of styrene …
functional substances. Herein, a two-component [4+ 2] annulation reaction of styrene …
Access to π-Extended Heterocycles Containing Pyrrolo-Coumarin Cores Involving− COCH3 as a Traceless Directing Group and Materializing Two Successive sp2C …
D Das, AR Das - The Journal of Organic Chemistry, 2022 - ACS Publications
An efficient protocol has been developed for the preparation of π-extended N-heterocycles
involving a Rh (III)-catalyzed C–H activation reaction starting from 3-acetamidocoumarins …
involving a Rh (III)-catalyzed C–H activation reaction starting from 3-acetamidocoumarins …
Rhodium-Catalyzed C2-Alkylation of Indoles with Cyclopropanols Using N,N-Dialkylcarbamoyl as a Traceless Directing Group
An efficient rhodium-catalyzed synthesis of C2-alkylated NH-free indoles has been achieved
from substituted indoles and cyclopropanols. The reaction allows the synthesis of various C2 …
from substituted indoles and cyclopropanols. The reaction allows the synthesis of various C2 …