The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

The synthesis of polymers with well-defined compositions, architectures, and functionalities
has long been of great interest in polymer chemistry. Typically, living polymerization …

Recent mechanistic developments in the field of controlled/living radical polymerization
(CRP) are reviewed. Particular emphasis is placed on structure–reactivity correlations and …

3689 Chem. Rev. 2001, 101, 3689− 3745 10.1021/cr9901182 CCC: $36.00© 2001
American Chemical Society Published on Web 12/12/2001 laboratory-scale processes for …

Precision control of radical polymerization, or living radical polymerization, has been among
the most important and long-waited subjects in polymer chemistry and macromolecular …

Virtually every branch of science, technology, and art uses a plethora of polymeric materials.
These include not only “pure” linear, branched, or cross-linked (gels, rubbers, etc.) polymers …

Single-Electron Transfer and Single-Electron Transfer Degenerative Chain Transfer Living
Radical Polymerization | Chemical Reviews Recently Viewedclose modal ACS ACS Publications …

Conventional free radical polymerization (RP) has many advantages (see Chapters 2–4
discussing specific polymers prepared by radical polymerization). The procedure can be …

The development of new controlled radical polymerization methods has progressed rapidly
over the last five years. One of the most useful of these methods, atom transfer radical …

The discovery, in the mid 1990s, that certain cobalt, ruthenium and copper complexes could
effectively control the radical polymerization of a number of polar olefins, allowing for the …