A chemical kinetic mechanism for 2‐bromo‐3, 3, 3‐trifluoropropene (2‐BTP) flame inhibition

DR Burgess Jr, VI Babushok… - … Journal of Chemical …, 2015 - Wiley Online Library
In this work, we report a detailed chemical kinetic mechanism to describe the flame inhibition
chemistry of the fire‐suppressant 2‐bromo‐3, 3, 3‐trifluoropropene (2‐BTP), under …

The oxidation of hydrogen and carbon monoxide

G Dixon-Lewis, DJ Williams - Comprehensive chemical kinetics, 1977 - Elsevier
Publisher Summary The chapter discusses the oxidation of hydrogen and carbon monoxide,
and discusses the oxidation of hydrogen–carbon monoxide mixtures. The kinetic …

Fluorocarbon oxy and peroxy radicals

S von Ahsen, H Willner, GA Argüello - Journal of fluorine chemistry, 2004 - Elsevier
This review deals with the most fundamental fluorocarbon oxy (x= 1) and peroxy (x= 2)
radicals CF3Ox, FC (O) Ox, CF3C (O) Ox and CF3OC (O) Ox. Their role in atmospheric and …

[LIVRE][B] Chemi-and bioluminescence

JG Burr - 2020 - books.google.com
This book focuses on instrumentation of chemi-and bioluminescence and discusses the
nature of chemiluminescence as the exothermic oxidation of a substrate organic compound …

IR and UV Spectra of the Matrix‐Isolated Peroxy Radicals CF3OO, trans‐FC(O)OO, and cis‐FC(O)OO

S Sander, H Pernice, H Willner - Chemistry–A European …, 2000 - Wiley Online Library
The peroxy radicals CF3OO and FC (O) OO are prepared in high yields by vacuum flash
pyrolysis of ROONO2 or ROOOR (R= CF3, FC (O)), highly diluted in inert gases, and …

Gas phase oxidation of perhalocarbons

J Heicklen - Advances in Photochemistry, 1969 - Wiley Online Library
The purpose of this article is to review critically the gas-phase oxidation of perhalocarbons
and to survey the work available as of April 1. 1967. Results in condensed phases or with …

Infrared diode laser spectroscopy of FCO: The ν1 and ν2 bands

K Nagai, C Yamada, Y Endo, E Hirota - Journal of Molecular Spectroscopy, 1981 - Elsevier
Abstract The ν 1 (C O stretching) and ν 2 (C F stretching) bands of the FCO radical were
observed with Doppler-limited resolution by an infrared diode laser spectrometer with …

Visible absorption spectroscopy of the B 2A1–X 2B2 transition of fluoroformyloxyl radical, FC (O) O

MM Maricq, JJ Szente, Z Li, JS Francisco - The Journal of chemical …, 1993 - pubs.aip.org
We report the visible absorption spectrum of the fluoroformyloxyl radical. The spectrum is
assigned to the B 2AI_X 2 B2 transition in FC (O) O. The origin of the excitation spectrum is …

Temperature dependent kinetics of the formation and self‐reactions of FC(O)O2 and FC(O)O radicals

MM Maricq, JJ Szente, GA Khitrov… - The Journal of chemical …, 1993 - pubs.aip.org
This paper presents the ultraviolet (UV) absorption spectrum of FC (O) O2 and the
temperature dependent rate constants for its formation via the addition of O2 to FCO, its self …

Infrared absorption spectra of bis (monofluorocarbonyl)—and bis (trifluoromethyl)—peroxides

AJ Arvia, PJ Aymonino - Spectrochimica Acta, 1962 - Elsevier
Infrared absorption spectra of gaseous (FCO) 2 O 2 and (F 3 C) 2 O 2 have been obtained in
the NaCl and KBr regions. By comparison with the spectra of F 2 CO and F 3 COF, most of …