Rational synthesis of atomically precise graphene nanoribbons directly on metal oxide surfaces
Atomically precise graphene nanoribbons (GNRs) attract great interest because of their
highly tunable electronic, optical, and transport properties. However, on-surface synthesis of …
highly tunable electronic, optical, and transport properties. However, on-surface synthesis of …
Alkyne benzannulations in the preparation of contorted nanographenes
KM Magiera, V Aryal, WA Chalifoux - Organic & Biomolecular …, 2020 - pubs.rsc.org
Nanographenes are a popular area of research due to their promising properties for
electronics. Over the last twenty years there has been a significant increase in interest in the …
electronics. Over the last twenty years there has been a significant increase in interest in the …
Twenty Years of Graphene: From Pristine to Chemically Engineered Nano-Sized Flakes
P Izquierdo-García… - Journal of the …, 2024 - ACS Publications
It is a celebratory moment for graphene! This year marks the 20th anniversary of the
discovery of this amazing material by Geim and Novoselov. Curiously, it coincides with the …
discovery of this amazing material by Geim and Novoselov. Curiously, it coincides with the …
Perylene‐Based Linear Nonalternant Nanoribbons with Bright Emission and Ambipolar Redox Behavior
Y Wang, Y Huang, T Huang, J Zhang… - Angewandte Chemie …, 2022 - Wiley Online Library
Here we report stepwise solution‐synthesis of linear nonalternant nanoribbons (NNRs),
featuring pentagonal rings peri‐fused onto the repeating perylene unit. The X‐ray single …
featuring pentagonal rings peri‐fused onto the repeating perylene unit. The X‐ray single …
Alumina-mediated π-activation of alkynes
The ability to induce powerful atom-economic transformation of alkynes is the key feature of
carbophilic π-Lewis acids such as gold-and platinum-based catalysts. The unique catalytic …
carbophilic π-Lewis acids such as gold-and platinum-based catalysts. The unique catalytic …
Single Crystal Growth of Cyclopenta-Fused Polycyclic Aromatic Hydrocarbon by the Naphthalene Flux Method: 2D Ambipolar Charge Transport Properties and NIR …
H Tanoguchi, T Yuki, S Yokokura… - ACS Applied …, 2023 - ACS Publications
Compared to simple p-and n-type organic field-effect transistors, it is very difficult to achieve
high performance in ambipolar transistors because both HOMO–HOMO and LUMO–LUMO …
high performance in ambipolar transistors because both HOMO–HOMO and LUMO–LUMO …
Cycl [2, 2, 4] azine-embedded non-alternant nanographenes containing fused antiaromatic azepine ring
L Ruan, W Luo, H Zhang, P Liu, Y Shi, P An - Chemical Science, 2024 - pubs.rsc.org
The development of non-alternant nanographenes has attracted considerable attention due
to their unique photophysical properties. Herein, we reported a novel aza-doped, non …
to their unique photophysical properties. Herein, we reported a novel aza-doped, non …
2,7,11,16‐Tetra‐tert‐Butyl Tetraindenopyrene Revisited by an “Inverse” Synthetic Approach
SM Elbert, A Haidisch, T Kirschbaum… - … A European Journal, 2020 - Wiley Online Library
A new synthetic route to tetraindenopyrene (TIP)—a bowl‐shaped cut‐out structure of C70—
is reported. The key step in this approach is a fourfold palladium‐catalyzed C− H activation …
is reported. The key step in this approach is a fourfold palladium‐catalyzed C− H activation …
Pitched π-Stacking Crystal Structure and Two-Dimensional Electronic Structure of Acenaphtho [1, 2-k] fluoranthene Analogues with Various Substituents
T Yuki, S Yokokura, M **, H Waizumi… - Crystal Growth & …, 2024 - ACS Publications
Electronic properties of organic semiconductors are governed by their crystal structures.
Rubrene, a high-mobility organic semiconductor, forms a pitched π-stacking structure. We …
Rubrene, a high-mobility organic semiconductor, forms a pitched π-stacking structure. We …
Acenaphthenoannulation Induced by the Dual Lewis Acidity of Alumina
V Akhmetov, M Feofanov… - … A European Journal, 2022 - Wiley Online Library
We have discovered a dual (ie, soft and hard) Lewis acidity of alumina that enables rapid
one‐pot π‐extension through the activation of terminal alkynes followed by C− F activation …
one‐pot π‐extension through the activation of terminal alkynes followed by C− F activation …