Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …
and selectivity. However, the structural complexity and vulnerability hamper the application …
Construction and application of base-stable MOFs: a critical review
Metal–organic frameworks (MOFs) are a new class of porous crystalline materials
constructed from organic ligands and metal ions/clusters. Owing to their unique advantages …
constructed from organic ligands and metal ions/clusters. Owing to their unique advantages …
Atomic-level design of metalloenzyme-like active pockets in metal–organic frameworks for bioinspired catalysis
Natural metalloenzymes with astonishing reaction activity and specificity underpin essential
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …
Simultaneous control of flexibility and rigidity in pore-space-partitioned metal–organic frameworks
Flexi-MOFs are typically limited to low-connected (< 9) frameworks. Here we report a
platform-wide approach capable of creating a family of high-connected materials …
platform-wide approach capable of creating a family of high-connected materials …
Metal–organic frameworks based on multicarboxylate linkers
When designing metal–organic frameworks (MOFs), linker design is one of the most
important factors in constructing a wide variety of structures. Judicious choice of linker size …
important factors in constructing a wide variety of structures. Judicious choice of linker size …
Chemistry of soft porous crystals: structural dynamics and gas adsorption properties
In this Minireview, we discuss the fundamental chemistry of soft porous crystals (SPCs) by
characterizing their common structural features and the resulting structural softness and …
characterizing their common structural features and the resulting structural softness and …
Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs
In the past two decades, reticular chemistry has developed into a powerful tool for the design
and synthesis of porous, crystalline framework materials. The discovery of the first …
and synthesis of porous, crystalline framework materials. The discovery of the first …
Reversed thermo-switchable molecular sieving membranes composed of two-dimensional metal-organic nanosheets for gas separation
It is highly desirable to reduce the membrane thickness in order to maximize the throughput
and break the trade-off limitation for membrane-based gas separation. Two-dimensional …
and break the trade-off limitation for membrane-based gas separation. Two-dimensional …
Metal–organic frameworks and porous organic polymers for sustainable fixation of carbon dioxide into cyclic carbonates
J Liang, YB Huang, R Cao - Coordination Chemistry Reviews, 2019 - Elsevier
The capture and chemical fixation of carbon dioxide (CO 2) into cyclic carbonates is
considered to be a promising way to alleviate CO 2 concerns and produce fine chemicals …
considered to be a promising way to alleviate CO 2 concerns and produce fine chemicals …
Advances in Mn‐based MOFs and their derivatives for high‐performance supercapacitor
H Cheng, J Li, T Meng, D Shu - Small, 2024 - Wiley Online Library
As the most widely used metal material in supercapacitors, manganese (Mn)‐based
materials possess the merits of high theoretical capacitance, stable structure as well as …
materials possess the merits of high theoretical capacitance, stable structure as well as …