Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

Metal–organic frameworks (MOFs) are a new class of porous crystalline materials
constructed from organic ligands and metal ions/clusters. Owing to their unique advantages …

This comprehensive review explores the diverse applications of defective zirconium-based
metal–organic frameworks (Zr-MOFs) in energy and environmental remediation. Zr-MOFs …

Natural metalloenzymes with astonishing reaction activity and specificity underpin essential
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …

In this Minireview, we discuss the fundamental chemistry of soft porous crystals (SPCs) by
characterizing their common structural features and the resulting structural softness and …

Flexi-MOFs are typically limited to low-connected (< 9) frameworks. Here we report a
platform-wide approach capable of creating a family of high-connected materials …

Separating ethane (C2H6) from ethylene (C2H4) is an essential and energy-intensive
process in the chemical industry. Here, we report two flexible diamondoid coordination …

In the past two decades, reticular chemistry has developed into a powerful tool for the design
and synthesis of porous, crystalline framework materials. The discovery of the first …

As the most widely used metal material in supercapacitors, manganese (Mn)‐based
materials possess the merits of high theoretical capacitance, stable structure as well as …

Metal-organic frameworks (MOFs) are an emerging class of porous materials composed of
metal ions or clusters interconnected by organic ligands. Many proposed applications for …