Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Enantioconvergent catalysis has expanded asymmetric synthesis to new methodologies
able to convert racemic compounds into a single enantiomer. This review covers recent …

An electrochemically driven nickel-catalyzed enantioselective reductive cross-coupling of
aryl aziridines with alkenyl bromides has been developed, affording enantioenriched β-aryl …

Herein, we designed a reaction for the desymmetrization–addition of cyclopropenes to
imines by leveraging the synergy between photoredox and asymmetric cobalt catalysis. This …

Substantial advances in enantioconvergent C (sp3)–C (sp3) bond formations have been
made with nickel-catalyzed cross-coupling of racemic alkyl electrophiles with organometallic …

Enantioselective metallaphotoredox catalysis, which combines photoredox catalysis and
asymmetric transition-metal catalysis, has become an effective approach to achieve …

The precise construction of chiral molecules is a core research area in chemical science and
technology. Among the plethora of reported synthetic methods, asymmetric catalysis has …

Chiral α-aryl N-heterocycles are commonly found in natural products, pharmaceutical
agents, and chiral catalysts but remain challenging to access via asymmetric catalysis …

Conspectus In recent years, nickel-catalyzed asymmetric coupling reactions have emerged
as efficient methods for constructing chiral C (sp3) carbon centers. Numerous novel …

The development of efficient catalytic multicomponent reactions (MCRs) is highly sought-
after in chemical synthesis. However, catalytic asymmetric MCRs, particularly involving …