Recent Developments with Organogermanes: their Preparation and Application in Synthesis and Catalysis

T Rogova, E Ahrweiler, MD Schoetz… - Angewandte …, 2024 - Wiley Online Library
Within the sphere of traditional Pd0/PdII cross coupling reactions, organogermanes have
been historically outperformed both in terms of scope and reactivity by more conventional …

Synthetic techniques for thermodynamically disfavoured substituted six-membered rings

Y Li, H Shi, G Yin - Nature Reviews Chemistry, 2024 - nature.com
Six-membered rings are ubiquitous structural motifs in bioactive compounds and
multifunctional materials. Notably, their thermodynamically disfavoured isomers, like …

Chemoselective Heterogeneous Hydrogenation of Sulfur Containing Quinolines under Mild Conditions

L Lückemeier, T De Vos, L Schlichter… - Journal of the …, 2024 - ACS Publications
Sulfur, alongside oxygen and nitrogen, holds a prominent position as one of the key
heteroatoms in nature and medicinal chemistry. Its significance stems from its ability to adopt …

Visible‐Light‐Driven Germyl Radical Generation via EDA‐Catalyzed ET–HAT Process

K Yoshizawa, BX Li, T Matsuyama… - … A European Journal, 2024 - Wiley Online Library
We have established a facile and efficient protocol for the generation of germyl radicals by
employing photo‐excited electron transfer (ET) in an electron donor‐acceptor (EDA) …

Arylgermylation of alkenes by a cooperative photoactivation and hydrogen atom transfer strategy

J Cao, Y Liu, Z Wang, L Liu - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
We present an efficient photoredox/HAT dual-catalyzed arylgermylation of alkenes using
readily available alkenes, germyl hydrides and (hetero) aryl nitriles under mild conditions …

Ni-catalyzed reductive alkylgermylation of activated alkenes: Modular access to polyfunctionalized alkyl germanes

YW Qiao, BQ Zhou, Y Huang - Chem Catalysis, 2023 - cell.com
Organogermanium compounds have played a significant role in organic synthesis, drug
discovery, and materials science. The efficient access to different types of organogermanium …

Arene Reduction by Rh/Pd or Rh/Pt under 1 atm Hydrogen Gas and Room Temperature

HX Li, ZX Yu - Organic Letters, 2024 - ACS Publications
Current methods for arene hydrogenation generally need either harsh reaction conditions or
complex catalyst preparation. Here we describe a mild and convenient protocol that only …

Visible-Light-Driven Silyl or Germyl Radical Generation via Si–C or Ge–C Bond Homolysis

BX Li, H Ishida, C Wang, M Uchiyama - Organic Letters, 2023 - ACS Publications
We report a simple, rapid, and selective protocol for visible-light-driven generation of silyl
radicals through photoredox-induced Si–C bond homolysis. Irradiating 3-silyl-1, 4 …

Rhodium-catalyzed double hydroboration of pyridine: the origin of the chemo-and regioselectivities

H Choi, R Wang, S Kim, D Kim, MH Baik… - Catalysis Science & …, 2023 - pubs.rsc.org
Rhodium-catalyzed hydroboration of unsaturated organic molecules is a well-established
reaction and conventionally operates via a Rh (I/III) cycle involving an inner-sphere hydride …

Cu-Catalyzed Asymmetric Hydrogermylation Towards C-and Ge-Stereogenic Germanes

W Lin, LQ Ren, C Du Chen, X Han, L Zhang… - CCS …, 2024 - chinesechemsoc.org
Organogermanium compounds have exhibited great application potential in the fields of
synthetic chemistry, materials science, and medicinal chemistry due to their unique …