Strong metal–support interaction in heterogeneous catalysts
Strong metal–support interaction (SMSI) in supported metal catalysts, typically accompanied
by the formation of encapsulation layers over metal nanoparticles, has drawn intense …
by the formation of encapsulation layers over metal nanoparticles, has drawn intense …
Role of the support in gold-containing nanoparticles as heterogeneous catalysts
M Sankar, Q He, RV Engel, MA Sainna… - Chemical …, 2020 - ACS Publications
In this review, we discuss selected examples from recent literature on the role of the support
on directing the nanostructures of Au-based monometallic and bimetallic nanoparticles. The …
on directing the nanostructures of Au-based monometallic and bimetallic nanoparticles. The …
Structure Sensitivity of Au‐TiO2 Strong Metal–Support Interactions
Strong metal–support interactions (SMSI) is an important concept in heterogeneous
catalysis. Herein, we demonstrate that the Au‐TiO2 SMSI of Au/TiO2 catalysts sensitively …
catalysis. Herein, we demonstrate that the Au‐TiO2 SMSI of Au/TiO2 catalysts sensitively …
O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …
Wet-chemistry strong metal–support interactions in titania-supported Au catalysts
J Zhang, H Wang, L Wang, S Ali, C Wang… - Journal of the …, 2019 - ACS Publications
Classical strong metal–support interactions (SMSI), which play a crucial role in the
preparation of supported metal nanoparticle catalysts, is one of the most important concepts …
preparation of supported metal nanoparticle catalysts, is one of the most important concepts …
Reactivity of metal clusters
Z Luo, AW Castleman Jr, SN Khanna - Chemical reviews, 2016 - ACS Publications
We summarize here the research advances on the reactivity of metal clusters. After a simple
introduction of apparatuses used for gas-phase cluster reactions, we focus on the reactivity …
introduction of apparatuses used for gas-phase cluster reactions, we focus on the reactivity …
Size-dependent strong metal-support interaction in TiO2 supported Au nanocatalysts
X Du, Y Huang, X Pan, B Han, Y Su, Q Jiang… - Nature …, 2020 - nature.com
The strong metal-support interaction (SMSI) has long been studied in heterogonous
catalysis on account of its importance in stabilizing active metals and tuning catalytic …
catalysis on account of its importance in stabilizing active metals and tuning catalytic …
Carbide-supported Au catalysts for water–gas shift reactions: a new territory for the strong metal–support interaction effect
J Dong, Q Fu, Z Jiang, B Mei, X Bao - Journal of the American …, 2018 - ACS Publications
Strong metal–support interaction (SMSI) has been regarded as one of the most important
concepts in heterogeneous catalysis, which has been almost exclusively discussed in …
concepts in heterogeneous catalysis, which has been almost exclusively discussed in …
Spectroscopic Observation of Dual Catalytic Sites During Oxidation of CO on a Au/TiO2 Catalyst
The prevailing view of CO oxidation on gold-titanium oxide (Au/TiO2) catalysts is that the
reaction occurs on metal sites at the Au/TiO2 interface. We observed dual catalytic sites at …
reaction occurs on metal sites at the Au/TiO2 interface. We observed dual catalytic sites at …
Catalysis by supported gold nanoparticles: beyond aerobic oxidative processes
1. INTRODUCTION Bulk gold, being the most stable among all metals, was for many years
considered as an inert catalyst. However, gold particles with size on the scale of nanometers …
considered as an inert catalyst. However, gold particles with size on the scale of nanometers …