Research Progress of Intramolecular π‐Stacked Small Molecules for Device Applications

SY Yang, YK Qu, LS Liao, ZQ Jiang… - Advanced …, 2022 - Wiley Online Library
Organic semiconductors can be designed and constructed in π‐stacked structures instead of
the conventional π‐conjugated structures. Through‐space interaction (TSI) occurs in π …

Efficient near-infrared luminescence of self-assembled platinum (II) complexes: from fundamentals to applications

YC Wei, KH Kuo, Y Chi, PT Chou - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Designing bright and efficient near-infrared (NIR) emitters has drawn much
attention due to numerous applications ranging from biological imaging, medical therapy …

Metal Centers as Nucleophiles: Oxymoron of Halogen Bond‐Involving Crystal Engineering

DM Ivanov, NA Bokach… - … –A European Journal, 2022 - Wiley Online Library
This review highlights recent studies discovering unconventional halogen bonding (HaB)
that involves positively charged metal centers. These centers provide their filled d‐orbitals …

Dinuclear PtII Complexes with Strong Blue Phosphorescence for Operationally Stable Organic Light‐Emitting Diodes with EQE up to 23 % at 1000 cd m−2

KW Lo, GSM Tong, G Cheng, KH Low… - Angewandte …, 2022 - Wiley Online Library
Here we describe the synthesis and characterization of a new class of dinuclear PtII
complexes with blue phosphorescence. Bulky N‐heterocyclic carbene and tethered bridging …

Highly efficient deep-blue phosphorescent OLEDs based on a trimethylsilyl-substituted tetradentate Pt (II) complex

HJ Park, JH Jang, JH Lee… - ACS Applied Materials & …, 2022 - ACS Publications
Compared to Ir (III) complexes with octahedral geometries, Pt (II) complexes with square
planar geometries show superior optical properties because their flat shapes lead to an …

Highly emissive dinuclear platinum (III) complexes

X Wu, DG Chen, D Liu, SH Liu, SW Shen… - Journal of the …, 2020 - ACS Publications
Dinuclear Pt (III) complexes were commonly reported to have short-lived lowest-lying triplet
states, resulting in extremely weak or no photoluminescence. To overcome this obstacle, a …

Metal‐Induced Planar Chirality of Soft‐Bridged Binuclear Platinum (II) Complexes: 100% Phosphorescence Quantum Yields, Chiral Self‐Sorting, and Circularly …

J Song, H **ao, B Zhang, L Qu, X Zhou… - Angewandte …, 2023 - Wiley Online Library
PtII complexes have attracted a great deal of interest due to their rich phosphorescent
properties. However, these square‐planar PtII complexes are far more likely to encounter …

Supramolecular Assembly of Metal Complexes by (Aryl)I⋅⋅⋅d [PtII] Halogen Bonds

EA Katlenok, M Haukka, OV Levin… - … A European Journal, 2020 - Wiley Online Library
The theoretical data for the half‐lantern complexes [{Pt ()(μ‐)} 2][1–3; is cyclometalated 2‐Ph‐
benzothiazole; is 2‐SH‐pyridine (1), 2‐SH‐benzoxazole (2), 2‐SH‐tetrafluorobenzothiazole …

Non-covalent intramolecular interactions through ligand-design promoting efficient photoluminescence from transition metal complexes

IO Koshevoy, M Krause, A Klein - Coordination Chemistry Reviews, 2020 - Elsevier
Ligand design allows arranging ligand entities and functional groups in order to generate a
plethora of non-covalent interactions such as π stacking, H bridging, and Lewis acid-base …

Incorporation of a Fluorine Atom in a Bridging Ligand of Half-Lantern PtII2 Complexes Provides up to 10-Fold Enhancement of Electroluminescence Brightness

EA Katlenok, DM Kryukov, AE Kurtsevich… - Inorganic …, 2023 - ACS Publications
The binuclear half-lantern platinum (II) complexes [Pt (pbt)(μ-S∧ N)] 2 (pbtH= 2-
phenylbenzothiazole, S∧ N= benzo [d] thiazole-2-thiolate Pt1, 6-fluorobenzo [d] thiazole-2 …