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Pushing the limit of 3d transition metal-based layered oxides that use both cation and anion redox for energy storage
Intercalation chemistry has dominated electrochemical energy storage for decades, and
storage capacity worldwide has now reached the terawatt-hour level. State-of-the-art …
storage capacity worldwide has now reached the terawatt-hour level. State-of-the-art …
Highly reversible local structural transformation enabled by native vacancies in O2-type Li-rich layered oxides with anion redox activity
H Liu, C Li, W Tong, B Hu - The Journal of Physical Chemistry …, 2023 - ACS Publications
A novel O2-phase Li1. 033Ni0. 2 [□ 0.1 Mn0. 5] O2 cathode with native vacancies (denoted
as “□”) was delicately designed. By a combination of noninvasive 7Li pj-MATPASS NMR …
as “□”) was delicately designed. By a combination of noninvasive 7Li pj-MATPASS NMR …
What triggers the voltage hysteresis variation beyond the first cycle in Li-rich 3d layered oxides with reversible cation migration?
H Liu, C Zhao, Q Qiu, B Hu, F Geng, J Li… - The Journal of …, 2021 - ACS Publications
Herein, the structure–electrochemistry relationship of O2-Li5/6 (Li0. 2Ni0. 2Mn0. 6) O2 is
deliberately studied by local-structure probes including site-sensitive 7Li pj-MATPASS NMR …
deliberately studied by local-structure probes including site-sensitive 7Li pj-MATPASS NMR …
Lithiation and Delithiation Dynamics of Different Li Sites in Li-Rich Battery Cathodes Studied by Operando Nuclear Magnetic Resonance
Li in Li-rich cathodes mostly resides at octahedral sites in both Li layers (LiLi) and transition
metal layers (LiTM). Extraction and insertion of LiLi and LiTM are strongly influenced by …
metal layers (LiTM). Extraction and insertion of LiLi and LiTM are strongly influenced by …
Structural and Electrochemical Kinetic Properties of 0.5Li2MnO3∙0.5LiCoO2 Cathode Materials with Different Li2MnO3 Domain Sizes
Lithium rich layered oxide xLi2MnO3∙(1− x) LiMO2 (M= Mn, Co, Ni, etc.) materials are
promising cathode materials for next generation lithium ion batteries. However, the …
promising cathode materials for next generation lithium ion batteries. However, the …
Sequential delithiation behavior and structural rearrangement of a nanoscale composite-structured Li1.2Ni0.2Mn0.6O2 during charge–discharge cycles
K Shimoda, K Yazawa, T Matsunaga, M Murakami… - Scientific Reports, 2020 - nature.com
Lithium-and manganese-rich layered oxides (LMRs) are promising positive electrode
materials for next-generation rechargeable lithium-ion batteries. Herein, the structural …
materials for next-generation rechargeable lithium-ion batteries. Herein, the structural …
Controlled atomic solubility in Mn‐rich composite material to achieve superior electrochemical performance for Li‐ion batteries
The quest for high energy density and high power density electrode materials for lithium‐ion
batteries has been intensified to meet strongly growing demand for powering electric …
batteries has been intensified to meet strongly growing demand for powering electric …
Strain-induced stabilization of charged state in Li-rich layered transition-metal oxide for Lithium-ion batteries
T Kawaguchi, M Sakaida, M Oishi… - The Journal of …, 2018 - ACS Publications
Li-rich layered oxide (LLO) is a promising cathode material for lithium-ion batteries because
of its large capacity in comparison with conventional layered rock-salt structure materials. In …
of its large capacity in comparison with conventional layered rock-salt structure materials. In …
Solid‐State NMR and EPR Characterization of Transition‐Metal Oxides for Electrochemical Energy Storage
Transition‐metal oxides are important cathode materials for rechargeable lithium‐ion
batteries. During the lithiation and de‐lithiation processes, even though the long‐range …
batteries. During the lithiation and de‐lithiation processes, even though the long‐range …
Superior rate capability and cycling stability in partially cation-disordered co-free Li-rich layered materials enabled by an initial activation process
Li-rich layered materials that have Co-free and Mn-rich 3d-transition metals have the
potential to increase the achievable energy density of batteries because they are …
potential to increase the achievable energy density of batteries because they are …