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Vibrational spectroscopic map, vibrational spectroscopy, and intermolecular interaction
Vibrational spectroscopy is an essential tool in chemical analyses, biological assays, and
studies of functional materials. Over the past decade, various coherent nonlinear vibrational …
studies of functional materials. Over the past decade, various coherent nonlinear vibrational …
Water dynamics in the hydration shells of biomolecules
The structure and function of biomolecules are strongly influenced by their hydration shells.
Structural fluctuations and molecular excitations of hydrating water molecules cover a broad …
Structural fluctuations and molecular excitations of hydrating water molecules cover a broad …
Strong electric field observed at the interface of aqueous microdroplets
Chemical reactions in aqueous microdroplets often exhibit unusual kinetic and
thermodynamic properties not observed in bulk solution. While an electric field has been …
thermodynamic properties not observed in bulk solution. While an electric field has been …
[HTML][HTML] How cations affect the electric double layer and the rates and selectivity of electrocatalytic processes
Electrocatalysis is central to the production of renewable fuels and high-value commodity
chemicals. The electrolyte and the electrode together determine the catalytic properties of …
chemicals. The electrolyte and the electrode together determine the catalytic properties of …
[PDF][PDF] Iodine migration and its effect on hysteresis in perovskite solar cells
DOI: 10.1002/adma. 201503832 while the ferroelectric domain polarization/depolarization
process is much faster, in the picosecond range.[23, 24] In addition, piezoresponse force …
process is much faster, in the picosecond range.[23, 24] In addition, piezoresponse force …
Measuring electric fields and noncovalent interactions using the vibrational stark effect
Conspectus Over the past decade, we have developed a spectroscopic approach to
measure electric fields inside matter with high spatial (< 1 Å) and field (< 1 MV/cm) …
measure electric fields inside matter with high spatial (< 1 Å) and field (< 1 MV/cm) …
Decoding chemical information from vibrational spectroscopy data: Local vibrational mode theory
Modern vibrational spectroscopy is more than just an analytical tool. Information about the
electronic structure of a molecule, the strength of its bonds, and its conformational flexibility …
electronic structure of a molecule, the strength of its bonds, and its conformational flexibility …
Extreme electric fields power catalysis in the active site of ketosteroid isomerase
Enzymes use protein architecture to impose specific electrostatic fields onto their bound
substrates, but the magnitude and catalytic effect of these electric fields have proven difficult …
substrates, but the magnitude and catalytic effect of these electric fields have proven difficult …
Excited-state proton coupled charge transfer modulated by molecular structure and media polarization
Charge and proton transfer reactions in the excited states of organic dyes can be coupled in
many different ways. Despite the complementarity of charges, they can occur on different …
many different ways. Despite the complementarity of charges, they can occur on different …
A two-directional vibrational probe reveals different electric field orientations in solution and an enzyme active site
The catalytic power of an electric field depends on its magnitude and orientation with respect
to the reactive chemical species. Understanding and designing new catalysts for …
to the reactive chemical species. Understanding and designing new catalysts for …